Atmospheric Spectroscopy and Photochemistry at Environmental Water Interfaces

被引：56

作者：

Zhong, J. ^{[1
]}

Kumar, M. ^{[1
]}

Anglada, J. M. ^{[2
]}

Martins-Costa, M. T. C. ^{[3
]}

Ruiz-Lopez, M. F. ^{[3
]}

Zeng, X. C. ^{[1
]}

Francisco, Joseph S. ^{[1
,4
,5
]}

机构：

[1] Univ Nebraska, Dept Chem, Lincoln, NE 68566 USA

[2] Consejo Super Invest Cient IQAC CSIC, Inst Quim Avancada Catalunya, Dept Quim Biol & Modelitzacio Mol, E-08034 Barcelona, Spain

[3] Univ Lorraine, Lab Struct & React Syst Mol Complexes SRSMC, CNRS, UMR 7019, BP 70239, F-54506 Vandoeuvre Les Nancy, France

[4] Univ Penn, Dept Earth & Environm Sci, Philadelphia, PA 19104 USA

[5] Univ Penn, Dept Chem, Philadelphia, PA 19104 USA

来源：

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, VOL 70 | 2019年 / 70卷

关键词：

air-water interface; atmospheric species; adsorption; spectroscopy; photochemistry; SUM-FREQUENCY GENERATION; POLYCYCLIC AROMATIC-HYDROCARBONS; MOLECULAR-DYNAMICS SIMULATIONS; VOLATILE ORGANIC-COMPOUNDS; ABSORPTION CROSS-SECTIONS; DELIQUESCED NABR AEROSOL; AIR/WATER INTERFACE; AB-INITIO; SULFUR-DIOXIDE; AMMONIA OXIDATION;

D O I：

10.1146/annurev-physchem-042018-052311

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The air-water interface is ubiquitous in nature, as manifested in the form of the surfaces of oceans, lakes, and atmospheric aerosols. The aerosol interface, in particular, can play a crucial role in atmospheric chemistry. The adsorption of atmospheric species onto and into aerosols modifies their concentrations and chemistries. Moreover, the aerosol phase allows otherwise unlikely solution-phase chemistry to occur in the atmosphere. The effect of the air-water interface on these processes is not entirely known. This review summarizes recent theoretical investigations of the interactions of atmosphere species with the air-water interface, including reactant adsorption, photochemistry, and the spectroscopy of reactants at the water surface, with an emphasis on understanding differences between interfacial chemistries and the chemistries in both bulk solution and the gas phase. The results discussed here enable an understanding of fundamental concepts that lead to potential air-water interface effects, providing a framework to understand the effects of water surfaces on our atmosphere.

引用

页码：45 / 69

页数：25