Intramolecular C-H insertion reactions of acetoxy Fischer carbene complexes

被引：0

作者：

Takeda, K

Okamoto, Y

Nakajima, A

Yoshii, E

Koizumi, T

机构：

来源：

SYNLETT | 1997年 / 10期

关键词：

C-H insertion; Fischer carbene complex; bicyclo[4.1.0]heptene; Diels-Alder reaction;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of 4-substituted 2-(t-butyldimethylsiloxy)-1,3-butadiene with acetoxy chromium Fischer carbene complexes afforded bicyclo[4.1.0]heptene derivative 3, 18, an intramolecular C-H insertion product of the initially formed Diels-Alder adduct 6. The role of the metal and the heteroatom ligand in the carbene complex, and of the substituent at 3-position in 6 on the C-H insertion has been examined.

引用

页码：1181 / &

页数：4

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