Intramolecular C-H insertion reactions of acetoxy Fischer carbene complexes

被引：0
|
作者：
Takeda, K
Okamoto, Y
Nakajima, A
Yoshii, E
Koizumi, T
机构：
来源：
SYNLETT | 1997年 / 10期
关键词：
C-H insertion; Fischer carbene complex; bicyclo[4.1.0]heptene; Diels-Alder reaction;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reaction of 4-substituted 2-(t-butyldimethylsiloxy)-1,3-butadiene with acetoxy chromium Fischer carbene complexes afforded bicyclo[4.1.0]heptene derivative 3, 18, an intramolecular C-H insertion product of the initially formed Diels-Alder adduct 6. The role of the metal and the heteroatom ligand in the carbene complex, and of the substituent at 3-position in 6 on the C-H insertion has been examined.
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收藏
页码：1181 / &
页数：4
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