Synthesis, characterization and crystal structure of dibenzyltin bis (dithiotetrahydropyrrolocarbamate)

Dibenzyltin bis(dithiotetrahydropyrrolocarbamate) was synthesized by the reaction of dibenzyltin dichloride with dithlotetrahydropyrrolocarbamite. The compound was characterized by elemental analysis, IR, H-1 NMR and MS. and the crystal structure was determined by X-ray single crystal diffraction. The crystal belongs to orthorhombic with space group Pccn, a = 2.1665 (6) nm, b = 0.9932 (3) nm, c = 1.1979 (3) nm, alpha = 90degrees, beta = 90degrees, gamma = 90degrees, Z = 2, V = 2.5777 (12) nm(3), D-e = 1.529g . cm(-3), mu(Mo Kalpha) = 1.330mm(-1), F(000) = 1208, R-1 = 0.0341, wR(2) = 0.0627. In the crystals, the structures consist of discrete molecules in which the tin atom is six-coordinate in a distorted octahedron configuration.