Hollow-Structured Mesoporous Materials: Chemical Synthesis, Functionalization and Applications

被引:695
作者
Li, Yongsheng [1 ]
Shi, Jianlin [1 ,2 ]
机构
[1] E China Univ Sci & Technol, Lab Low Dimens Mat Chem, Sch Mat Sci & Engn, Key Lab Ultrafine Mat,Minist Educ, Shanghai 200237, Peoples R China
[2] Chinese Acad Sci, State Key Lab High Performance Ceram & Superfine, Shanghai Inst Ceram, Shanghai 200050, Peoples R China
关键词
CORE/MESOPOROUS SHELL CARBON; EFFICIENT CATALYST SUPPORT; SILICA SPHERES; FACILE FABRICATION; SPHERICAL CARBON; MOLECULAR-SIEVES; DRUG-DELIVERY; INORGANIC NANOPARTICLES; HETEROGENEOUS CATALYST; TITANIA MICROSPHERES;
D O I
10.1002/adma.201305319
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hollow-structured mesoporous materials (HMMs), as a kind of mesoporous material with unique morphology, have been of great interest in the past decade because of the subtle combination of the hollow architecture with the mesoporous nanostructure. Benefitting from the merits of low density, large void space, large specific surface area, and, especially, the good biocompatibility, HMMs present promising application prospects in various fields, such as adsorption and storage, confined catalysis when catalytically active species are incorporated in the core and/or shell, controlled drug release, targeted drug delivery, and simultaneous diagnosis and therapy of cancers when the surface and/or core of the HMMs are functionalized with functional ligands and/or nanoparticles, and so on. In this review, recent progress in the design, synthesis, functionalization, and applications of hollow mesoporous materials are discussed. Two main synthetic strategies, soft-templating and hard-templating routes, are broadly sorted and described in detail. Progress in the main application aspects of HMMs, such as adsorption and storage, catalysis, and biomedicine, are also discussed in detail in this article, in terms of the unique features of the combined large void space in the core and the mesoporous network in the shell. Functionalization of the core and pore/outer surfaces with functional organic groups and/or nanoparticles, and their performance, are summarized in this article. Finally, an outlook of their prospects and challenges in terms of their controlled synthesis and scaled application is presented.
引用
收藏
页码:3176 / 3205
页数:30
相关论文
共 232 条
[1]   Study of a fluorometric-enzymatic method for bilirubin based on chemically modified bilirubin-oxidase and multivariate calibration [J].
Andreu, Y ;
Ostra, M ;
Ubide, C ;
Galbán, J ;
de Marcos, S ;
Castillo, JR .
TALANTA, 2002, 57 (02) :343-353
[2]  
[Anonymous], ANGEW CHEM INT ED, DOI DOI 10.1002/ANGE.201001252
[3]  
Antonietti M, 1998, ADV MATER, V10, P154, DOI 10.1002/(SICI)1521-4095(199801)10:2<154::AID-ADMA154>3.0.CO
[4]  
2-I
[5]   One-pot aerosol synthesis of ordered hierarchical mesoporous core-shell silica nanoparticles [J].
Areva, S ;
Boissière, C ;
Grosso, D ;
Asakawa, T ;
Sanchez, C ;
Lindén, M .
CHEMICAL COMMUNICATIONS, 2004, (14) :1630-1631
[6]   High-temperature-stable catalysts by hollow sphere encapsulation [J].
Arnal, Pablo M. ;
Comotti, Massimiliano ;
Schueth, Ferdi .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (48) :8224-8227
[7]   Bilirubin adsorption property of sol-gel-derived titania particles for blood purification therapy [J].
Asano, Takuji ;
Tsuru, Kanji ;
Hayakawa, Satoshi ;
Osaka, Akiyoshi .
ACTA BIOMATERIALIA, 2008, 4 (04) :1067-1072
[8]   Catalytic characterization of mesoporous Ti-silica hollow spheres [J].
Baca, M. ;
Li, W. J. ;
Du, P. ;
Mul, G. ;
Moulijn, J. A. ;
Coppens, M. -O. .
CATALYSIS LETTERS, 2006, 109 (3-4) :207-210
[9]   A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].
BECK, JS ;
VARTULI, JC ;
ROTH, WJ ;
LEONOWICZ, ME ;
KRESGE, CT ;
SCHMITT, KD ;
CHU, CTW ;
OLSON, DH ;
SHEPPARD, EW ;
MCCULLEN, SB ;
HIGGINS, JB ;
SCHLENKER, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843
[10]   High performance supercapacitor prepared from hollow mesoporous carbon capsules with hierarchical nanoarchitecture [J].
Bhattacharjya, Dhrubajyoti ;
Kim, Min-Sik ;
Bae, Tae-Sung ;
Yu, Jong-Sung .
JOURNAL OF POWER SOURCES, 2013, 244 :799-805