Assembly of Cu(I) Alkynyl Complexes: From Cluster to Infinite Cluster-Based Framework

被引：10

作者：

Xie, Yun-Peng ^{[1
]}

Wen, Jun-Bo ^{[1
]}

Pan, Chang-Wang ^{[1
]}

Duan, Guang-Xiong ^{[1
]}

Li, Lan-Yun ^{[1
]}

Lu, Xing ^{[1
]}

机构：

[1] HUST, State Key Lab Mat Proc & Die & Mould Technol, Sch Mat Sci & Engn, Wuhan 430074, Hubei, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2019年 / 19卷 / 10期

基金：

中国国家自然科学基金;

关键词：

IN-SITU SYNTHESIS; C BOND-CLEAVAGE; COORDINATION POLYMERS; MULTINUCLEAR SILVER(I); COPPER(I) COMPLEXES; CRYSTAL-STRUCTURE; LUMINESCENT; GOLD(I); NANOCLUSTER; ACETYLIDES;

D O I：

10.1021/acs.cgd.9b00803

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Variation of the reaction conditions with Cu powder, Cu(NO3)(2), and (BuC)-Bu-t CH as starting materials afforded three new Cu(I) alkynyl complexes, namely, [Cu-14((BuC)-Bu-t C)(10)(NO3)(4)(MeOH)(2)]center dot H2O (1), Cu-15((BuC)-Bu-t C)(14)(NO3) (2), and [Cu-14((BuC)-Bu-t C)(8)(NO3)(2)(CN)(4)](n) (3). Single-crystal X-ray analysis revealed that clusters 1 and 2 consist of Cu-14 and Cu-15 cores costabilized by strong by sigma- and pi-bonded tert-butylethynides and nitrates. Complex 3 displays an intriguing three-dimensional cyano-bridged Cu(I) alkynyl cluster-based framework, in which the existence of CN- is assumed to have originated from the Cu(I)-mediated C-C cleavage reaction of acetonitrile under mild solvothermal conditions.

引用

页码：5791 / 5797

页数：7

共 72 条

[1] Copper(I) alkynyl clusters, [Cux+y(hfac)x(C=CR)y], with CU10-CU12 cores [J].

Baxter, Christopher W. ;

Higgs, Timothy C. ;

Bailey, Philip J. ;

Parsons, Simon ;

McLachlan, Fiona ;

McPartlin, Mary ;

Tasker, Peter A. .

CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (23) :6166-6174

[2] Luminescent high nuclearity Cu(I)-alkynyl clusters, [Cu16(hfac)8(3,3-dimethyl-1-butynyl)8] and [Cu20(hfac)8(3-phenyl-1-propynyl)12] [J].

Baxter, CW ;

Ffiggs, TC ;

Jones, AC ;

Parsons, S ;

Bailey, PJ ;

Tasker, PA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (23) :4395-4401

[3] From Cluster to Polymer: Ligand Cone Angle Controlled Syntheses and Structures of Copper(I) Alkynyl Complexes [J].

Chang, Xiao-Yong ;

Low, Kam-Hung ;

Wang, Juan-Yu ;

Huang, Jie-Sheng ;

Che, Chi-Ming .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (35) :10312-10316

[4] Luminescent μ-ethynediyl and μ-butadiynediyl binuclear gold(I) complexes:: Observation of 3(ππ*) emissions from bridging Cn2- units [J].

Che, CM ;

Chao, HY ;

Miskowski, VM ;

Li, YQ ;

Cheung, KK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (21) :4985-4991

[5] Luminescent and Magnetic Cyano-Bridged Coordination Polymers Containing 4d-4f Ions: Toward Multifunctional Materials [J].

Chelebaeva, Elena ;

Larionova, Joulia ;

Guari, Yannick ;

Ferreira, Rute A. S. ;

Carlos, Luis D. ;

Almeida Paz, Filipe A. ;

Trifonov, Alexander ;

Guerin, Christian .

INORGANIC CHEMISTRY, 2009, 48 (13) :5983-5995

[6] Capturing the Organic Species Derived from the C-C Cleavage and in Situ Oxidation of 1,2,3,4-Tetra(pyridin-4-yl)cyclobutane by [CuCN]n-Based MOFs [J].

Chen, Liang ;

Li, Hong-Xi ;

Da, Ming ;

Li, Hai-Yan ;

Lang, Jian-Ping .

INORGANIC CHEMISTRY, 2018, 57 (15) :9160-9166

[7] Structure determination of homoleptic AuI, AgI, and CuI aryl/alkylethynyl coordination polymers by X-ray powder diffraction [J].

Chui, SSY ;

Ng, MFY ;

Che, CM .

CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (06) :1739-1749

[8] Synthesis and Structure of a Cyanoaurate-Based Organotin Polymer Exhibiting Unusual Ion-Exchange Properties [J].

Deak, Andrea ;

Tunyogi, Tuende ;

Palinkas, Gabor .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (08) :2815-+

[9] An atomically precise all-tert-butylethynide-protected Ag51 superatom nanocluster with color tunability [J].

Duan, Guang-Xiong ;

Tian, Lin ;

Wen, Jun-Bo ;

Li, Lan-Yun ;

Xie, Yun-Peng ;

Lu, Xing .

NANOSCALE, 2018, 10 (40) :18915-18919

[10] High-Nuclearity Heterometallic tert-Butylethynide Clusters Assembled with tert-Butylphosphonate [J].

Duan, Guang-Xiong ;

Xie, Yun-Peng ;

Jin, Jun-Ling ;

Bao, Li-Piao ;

Lu, Xing ;

Mak, Thomas C. W. .

CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (26) :6762-6768

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