Enthalpic pair interaction coefficients in DMF solution .3. Thermochemistry of NaI solutions in mixtures of N,N-dimethylformamide with urea, formamide, acetamide and N,N-dimethylacetamide at 298.15 K

被引:15
|
作者
Piekarski, H
Waliszewski, D
机构
[1] Department of Physical Chemistry, University of Łódz, 91-416 Łódz
来源
JOURNAL OF THERMAL ANALYSIS | 1996年 / 47卷 / 06期
关键词
acetamide; dissolution enthalpies of NaI; DMF mixtures; enthalpic pair interaction coefficients; formamide; N; N-dimethylacetamide; urea;
D O I
10.1007/BF01980910
中图分类号
O414.1 [热力学];
学科分类号
摘要
Dissolution enthalpies of NaI in mixtures of N,N-dimethylformamide with urea, formamide, acetamide and N,N-dimethylacetamide were measured. The results were compared with data measured earlier for other DMF - non-electrolyte mixtures. The enthalpic pair interaction coefficients, h(xy) (Na+I- - non-electrolyte) in DMF were calculated and analysed together with the appropriate data concerning other Na+I- - non-electrolyte pairs in DME The group interaction coefficients illustrating the interactions of Na+I- with the CH2, OH, O, CO, 'Pep' and 'iPep' groups were determined and discussed.
引用
收藏
页码:1639 / 1647
页数:9
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