The studies of free radical reactions by using time-resolved FTIR emission Spectroscopy

被引：0

作者：

Kong, FA ^{[1
]}

Dong, F ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Lab Mol React Dynam, Beijing 100080, Peoples R China

来源：

CHINESE JOURNAL OF CHEMICAL PHYSICS | 2004年 / 17卷 / 03期

关键词：

time-resolved; infrared spectrum; free radical reactions; gaseous phase;

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

In the past fifteen years, free radical reactions in the gaseous phase have been widely studied by time-resolved fourier transform spectroscopy. Sloan et al. first investigated O(D-1) reactions and then Leone and Hancock groups studied O(P-3) reactions. Later, Kong, Zhu et al. investigated small radical, including CH, CH,, CH3, C2H3, C2H5, C2H, C3H3 and C3H5, reacting with the molecules of O-2, NO, N2O, NO2. For each reaction, nascent products and primary channels are observed in the IR spectrum. Combining with ab initio theoretical investigations, the reaction mechanisms are almost understood.

引用

页码：225 / 232

页数：8

共 46 条

[1] THE INITIAL PRODUCT VIBRATIONAL-ENERGY DISTRIBUTION IN THE REACTION BETWEEN O(1D2) AND H2 [J].

AKER, PM ;

SLOAN, JJ .

JOURNAL OF CHEMICAL PHYSICS, 1986, 85 (03) :1412-1417

[2] THE DYNAMICS OF THE REACTION OF O(D-1) WITH HBR STUDIED BY CROSSED MOLECULAR-BEAMS AND TIME-RESOLVED FOURIER-TRANSFORM SPECTROSCOPY [J].

BALUCANI, N ;

BENEVENTI, L ;

CASAVECCHIA, P ;

VOLPI, GG ;

KRUUS, EJ ;

SLOAN, JJ .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1994, 72 (03) :888-902

[3] THE EFFECT OF REAGENT TRANSLATIONAL EXCITATION ON THE DYNAMICS OF THE REACTION H+CL-2-]HCL(V',J')+CL [J].

BERG, PA ;

SLOAN, JJ .

JOURNAL OF CHEMICAL PHYSICS, 1994, 100 (02) :1075-1084

[4] The CF3+NO2 rate constant measured between 1.5 and 110 Torr and between 251 and 295 K by time resolved infrared emission [J].

Breheny, C ;

Hancock, G ;

Morrell, C .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2000, 2 (22) :5105-5112

[5] The rate constant for the recombination reaction between CF3 and O2 measured between 2 and 110 torr [J].

Breheny, Ciara ;

Hancock, Gus ;

Morrell, Claire .

2001, Oldenbourg Wissenschaftsverlag GmbH (215)

[6] Infrared emission from the reaction of CHF ((X)over-tilde-(1)A') with NO [J].

Brownsword, RA ;

Hancock, G ;

Oum, KW .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (12) :4840-4847

[7] TIME-RESOLVED FOURIER-TRANSFORM INFRARED-EMISSION IN THE O(3P) + CHF(1A') REACTION [J].

BROWNSWORD, RA ;

HANCOCK, G ;

HEARD, DE .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1991, 87 (15) :2283-2289

[8] Time-resolved FTIR emission study of product dynamics in the NO+NCO reaction [J].

Brownsword, RA ;

Hancock, G .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1997, 93 (07) :1279-1286

[9] DYNAMICS OF CO FORMATION IN THE REACTION O(P-3)+C2H3 [J].

DONALDSON, DJ ;

OKUDA, IV ;

SLOAN, JJ .

CHEMICAL PHYSICS, 1995, 193 (1-2) :37-45

[10] The reaction of formaldehyde with chlorine atom [J].

Dong, F ;

Qu, ZW ;

Zhang, QY ;

Kong, F .

CHEMICAL PHYSICS LETTERS, 2003, 371 (1-2) :29-34

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