Synthesis and CO2 Adsorption Properties of Hydrophobic Porous Coordination Polymer Featuring [Zn9(MeBTZ)12]6+ Building Units

被引：3
作者：
Watabe, Tsuyoshi [1 ]
Yogo, Katsunori [1 ,2 ]
机构：
[1] Res Inst Innovat Technol Earth, Chem Res Grp, Kyoto 6190292, Japan
[2] Nara Inst Sci & Technol, Grad Sch Mat Sci, Nara 6300192, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2014年 / 87卷 / 06期
关键词：
METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE CAPTURE; WATER; CHEMISTRY; STABILITY; STORAGE; DESIGN; GAS;
D O I：
10.1246/bcsj.20130153
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A hydrophobic porous coordination polymer, [Zn-9(MeBTZ)(12)(BPDC)(3)] where MeBTZ is 5-methylbenzotriazolate and BPDC is 4,4'-biphenyldicarboxylate, was obtained through a one-pot solvothermal reaction of zinc nitrate hexahydrate, 5-methyl-1H-benzotriazole and 4,4'-biphenyldicarboxylic acid in N,N-dimethylacetamide. The structure of [Zn-9(MeBTZ)(12)(BPDC)(3)] was built from trigonal antiprismatic [Zn-9(MeBTZ)(12)](6+) nodes connected with linear BPDC linkers, having 4(6)6(9) net topology. The working capacity for CO2 adsorption on [Zn-9(MeBTZ)(12)(BPDC)(3)] over the pressure range between 0.1 and 1.6 MPa at 40 degrees C was 3.4 mol kg(-1) after the preintroduction of high humidity.
引用
收藏
页码：740 / 745
页数：6
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