Synthesis and CO2 Adsorption Properties of Hydrophobic Porous Coordination Polymer Featuring [Zn9(MeBTZ)12]6+ Building Units

被引：3

作者：

Watabe, Tsuyoshi ^{[1
]}

Yogo, Katsunori ^{[1
,2
]}

机构：

[1] Res Inst Innovat Technol Earth, Chem Res Grp, Kyoto 6190292, Japan

[2] Nara Inst Sci & Technol, Grad Sch Mat Sci, Nara 6300192, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2014年 / 87卷 / 06期

关键词：

METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE CAPTURE; WATER; CHEMISTRY; STABILITY; STORAGE; DESIGN; GAS;

D O I：

10.1246/bcsj.20130153

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A hydrophobic porous coordination polymer, [Zn-9(MeBTZ)(12)(BPDC)(3)] where MeBTZ is 5-methylbenzotriazolate and BPDC is 4,4'-biphenyldicarboxylate, was obtained through a one-pot solvothermal reaction of zinc nitrate hexahydrate, 5-methyl-1H-benzotriazole and 4,4'-biphenyldicarboxylic acid in N,N-dimethylacetamide. The structure of [Zn-9(MeBTZ)(12)(BPDC)(3)] was built from trigonal antiprismatic [Zn-9(MeBTZ)(12)](6+) nodes connected with linear BPDC linkers, having 4(6)6(9) net topology. The working capacity for CO2 adsorption on [Zn-9(MeBTZ)(12)(BPDC)(3)] over the pressure range between 0.1 and 1.6 MPa at 40 degrees C was 3.4 mol kg(-1) after the preintroduction of high humidity.

引用

页码：740 / 745

页数：6

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