Synthesis and CO2 Adsorption Properties of Hydrophobic Porous Coordination Polymer Featuring [Zn9(MeBTZ)12]6+ Building Units

被引：3
作者：
Watabe, Tsuyoshi [1 ]
Yogo, Katsunori [1 ,2 ]
机构：
[1] Res Inst Innovat Technol Earth, Chem Res Grp, Kyoto 6190292, Japan
[2] Nara Inst Sci & Technol, Grad Sch Mat Sci, Nara 6300192, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2014年 / 87卷 / 06期
关键词：
METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE CAPTURE; WATER; CHEMISTRY; STABILITY; STORAGE; DESIGN; GAS;
D O I：
10.1246/bcsj.20130153
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A hydrophobic porous coordination polymer, [Zn-9(MeBTZ)(12)(BPDC)(3)] where MeBTZ is 5-methylbenzotriazolate and BPDC is 4,4'-biphenyldicarboxylate, was obtained through a one-pot solvothermal reaction of zinc nitrate hexahydrate, 5-methyl-1H-benzotriazole and 4,4'-biphenyldicarboxylic acid in N,N-dimethylacetamide. The structure of [Zn-9(MeBTZ)(12)(BPDC)(3)] was built from trigonal antiprismatic [Zn-9(MeBTZ)(12)](6+) nodes connected with linear BPDC linkers, having 4(6)6(9) net topology. The working capacity for CO2 adsorption on [Zn-9(MeBTZ)(12)(BPDC)(3)] over the pressure range between 0.1 and 1.6 MPa at 40 degrees C was 3.4 mol kg(-1) after the preintroduction of high humidity.
引用
收藏
页码：740 / 745
页数：6
相关论文
共 41 条
  • [1] Reaction of diacetylmonoxime with morpholine N-thiohydrazide in the absence and in presence of a metal ion: Facile synthesis of a thiadiazole derivative with non-bonded S...S interaction
    Biswas, Susobhan
    Yap, Glenn P. A.
    Dey, Kamalendu
    [J]. POLYHEDRON, 2009, 28 (14) : 3094 - 3100
  • [2] The effect of water on the adsorption of CO2 and C3H8 on type X zeolites
    Brandani, F
    Ruthven, DM
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2004, 43 (26) : 8339 - 8344
  • [3] Reversible Structural Change of Cu-MOF on Exposure to Water and Its CO2 Adsorptivity
    Cheng, Yan
    Kondo, Atsushi
    Noguchi, Hiroshi
    Kajiro, Hiroshi
    Urita, Koki
    Ohba, Tomonori
    Kaneko, Katsumi
    Kanoh, Hirofumi
    [J]. LANGMUIR, 2009, 25 (08) : 4510 - 4513
  • [4] CHESTER AW, 2000, Patent No. 6136291
  • [5] COMPARISON OF ACTIVATED CARBON AND ZEOLITE 13X FOR CO2 RECOVERY FROM FLUE-GAS BY PRESSURE SWING ADSORPTION
    CHUE, KT
    KIM, JN
    YOO, YJ
    CHO, SH
    YANG, RT
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1995, 34 (02) : 591 - 598
  • [6] Carbon Dioxide Capture: Prospects for New Materials
    D'Alessandro, Deanna M.
    Smit, Berend
    Long, Jeffrey R.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (35) : 6058 - 6082
  • [7] Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks
    Deng, Hexiang
    Doonan, Christian J.
    Furukawa, Hiroyasu
    Ferreira, Ricardo B.
    Towne, John
    Knobler, Carolyn B.
    Wang, Bo
    Yaghi, Omar M.
    [J]. SCIENCE, 2010, 327 (5967) : 846 - 850
  • [8] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks
    Eddaoudi, M
    Moler, DB
    Li, HL
    Chen, BL
    Reineke, TM
    O'Keeffe, M
    Yaghi, OM
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) : 319 - 330
  • [9] Reducing the cost of CO2 capture from flue gases using pressure swing adsorption
    Ho, Minh T.
    Allinson, Guy W.
    Wiley, Dianne E.
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2008, 47 (14) : 4883 - 4890
  • [10] Horike S, 2009, NAT CHEM, V1, P695, DOI [10.1038/nchem.444, 10.1038/NCHEM.444]
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