Preparation of sol-gel nano-composites containing copper oxide and their gas sensing properties

被引:31
作者
Dutta, A
Das, D
Grilli, ML
Di Bartolomeo, E
Traversa, E
Chakravorty, D
机构
[1] Univ Roma Tor Vergata, Dipartimento Sci & Tecnol Chim, INSTM, I-00133 Rome, Italy
[2] Indian Assoc Cultivat Sci, Kolkata 700032, W Bengal, India
关键词
nano-composite; copper oxide; gas sensor;
D O I
10.1023/A:1020706707243
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Sol-gel derived composite materials were prepared with nano-sized copper particles in silica matrix. Nano-sized oxide coatings were grown on the nano-particles of copper by subjecting the composites to a controlled oxidation treatment at different temperatures. The current response of samples with oxide layers of different thickness were studied at fixed temperatures in the range 350-450degreesC in the presence of different concentrations of CO and NO2. The nano-composites were sensitive to both the gases. The operating temperature and the oxide thickness were found to have significant effect on the sensing properties.
引用
收藏
页码:1085 / 1089
页数:5
相关论文
共 8 条
[1]   Analysis of the noble metal catalytic additives introduced by impregnation of as obtained SnO2 sol-gel nanocrystals for gas sensors [J].
Cabot, A ;
Arbiol, J ;
Morante, JR ;
Weimar, U ;
Bârsan, N ;
Göpel, W .
SENSORS AND ACTUATORS B-CHEMICAL, 2000, 70 (1-3) :87-100
[2]  
Chiang YM, 1997, J ELECTROCERAM, V1, P205, DOI 10.1023/A:1009958625841
[3]   Synthesis of nanocrystalline nickel oxide by controlled oxidation of nickel nanoparticles and their humidity sensing properties [J].
Das, D ;
Pal, M ;
Di Bartolomeo, E ;
Traversa, E ;
Chakravorty, D .
JOURNAL OF APPLIED PHYSICS, 2000, 88 (11) :6856-6860
[4]   Interfacial conduction in silica gels containing nanocrystalline copper oxide [J].
Das, D ;
Chakravorty, D .
APPLIED PHYSICS LETTERS, 2000, 76 (10) :1273-1275
[5]   Control of Optical Properties of Gel-Derived Oxide Coating Films Containing Fine Metal Particles [J].
Kozuka, H. ;
Zhao, G. ;
Sakka, S. .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 1994, 2 (1-3) :741-744
[6]   NANOCOMPOSITE FILMS OF LEAD-ZIRCONATE-TITANATE AND METALLIC NICKEL BY SOL-GEL ROUTE [J].
KUNDU, TK ;
CHAKRAVORTY, D .
APPLIED PHYSICS LETTERS, 1995, 66 (26) :3576-3578
[7]   Basic aspects and challenges of semiconductor gas sensors [J].
Shimizu, Y ;
Egashira, M .
MRS BULLETIN, 1999, 24 (06) :18-24
[8]   Effect of particle size and dopant on properties of SnO2-based gas sensors [J].
Zhang, G ;
Liu, ML .
SENSORS AND ACTUATORS B-CHEMICAL, 2000, 69 (1-2) :144-152