A synthetic model for the oxygen-evolving complex in Sr2+-containing photosystem II

被引：24

作者：

Chen, Changhui ^{[1
]}

Zhang, Chunxi ^{[2
]}

Dong, Hongxing ^{[1
]}

Zhao, Jingquan ^{[2
]}

机构：

[1] Harbin Engn Univ, Coll Mat Sci & Chem Engn, Minist Educ, Key Lab Superlight Mat & Surface Technol,Polymer, Harbin 150001, Peoples R China

[2] Chinese Acad Sci, Inst Chem, Lab Photochem, Beijing 100190, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 66期

基金：

中国国家自然科学基金;

关键词：

MANGANESE-CALCIUM CLUSTER; WATER OXIDATION; STRUCTURAL MODELS; CRYSTAL-STRUCTURE; MECHANISM; STATES; RESOLUTION; RELEVANCE; CORE; S-2;

D O I：

10.1039/c4cc02349h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel heterometallic MnSr complex containing the Mn3SrO4 cuboidal moiety and all types of mu-O2- moieties observed in the oxygen-evolving complex (OEC) in Sr2+-containing photosystem II (PSII) has been synthesized and characterized, which provides a new synthetic model of the OEC.

引用

页码：9263 / 9265

页数：3

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