Solvent-free synthesis of decyl D-glycopyranosides under focused microwave irradiation

被引：81

作者：

Limousin, C ^{[1
]}

Cleophax, J ^{[1
]}

Petit, A ^{[1
]}

Loupy, A ^{[1
]}

Lukacs, G ^{[1
]}

机构：

[1] UNIV PARIS 11,ICMO,CNRS,LAB REACT SELECT SUPPORTS,F-91405 ORSAY,FRANCE

来源：

JOURNAL OF CARBOHYDRATE CHEMISTRY | 1997年 / 16卷 / 03期

关键词：

D O I：

10.1080/07328309708006533

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A three step microwave assisted solvent-free synthesis of decyl D-glucopyranoside with l-decanol was established for D-glucose and extended to D-galactose, D-mannose and N-troc-D-glucosamine with 70% average overall yield for the three steps (peracetylation, glycosylation and saponification). Rate enhancements and reduction of the reaction time were observed for the two last steps carried out under microwave irradiation when compared to conventional heating in the same conditions.

引用

页码：327 / 342

页数：16

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