Crystalinity Behaviour in Poly(ε-caprolactone)-b-Poly(dimethylsiloxane) Diblock and Triblock Copolymers through FTIR and DSC

被引：0

作者：

Gordin, Claudia ^{[1
]}

Rusu, Mihai ^{[1
]}

Delaite, Christelle ^{[2
]}

Salhi, Slim ^{[2
]}

Elzein, Tamara ^{[2
]}

Brogly, Maurice ^{[2
]}

机构：

[1] Gh Asachi Tech Univ Iasi, Fac Chem Engn, Iasi 700050, Romania

[2] Univ Haute Alsace, Lab Chim Organ & Bioorgan, UMR 7015, F-68093 Mulhouse, France

来源：

MATERIALE PLASTICE | 2009年 / 46卷 / 01期

关键词：

coordinated anionic ring-opening polymerization; block copolymer; crystallization; BLOCK-COPOLYMERS; POLYMER BLENDS; PDMS; MORPHOLOGIES; SILOXANE;

D O I：

暂无

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Well-defined block poly(epsilon-caprolactone)-b-poly(dimethiylsiloxane) (PCL-b-PDMS) copolymers with one or two PCL blocks were obtained via coordinated anionic polymerization of epsilon-caprolactone by using hydroxy terminated PDMS oligomers both as initiators and comonomers. Molecular weights of these copolymers were varied over a wide range between 7200 and 30400 g/mol and the formation. of copolymers with desired backbone composition were monitored by H-1 NMR spectroscopy and SEC. DSC studies illustrated the formation of two phase morphologies, with PDMS and PCL transitions respectively and the influence of the copolymers structure on. their thermal properties has been examined.

引用

页码：37 / 42

页数：6

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