Stable N-functionalised 'pincer' bis carbene ligands and their ruthenium complexes; synthesis and catalytic studies

被引：211

作者：

Danopoulos, AA ^{[1
]}

Winston, S

Motherwell, WB

机构：

[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

[2] UCL, Christopher Ingold Labs, London WC1H 0AJ, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 13期

关键词：

D O I：

10.1039/b202814j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Deprotonation of 2,6- bis( arylimidazolium) pyridine dibromide with KN( SiMe3)(2) gave thermally stable 2,6-bis(arylimidazol-2-ylidene) pyridine, which was further used to prepare ruthenium 'pincer' complexes; the latter show catalytic activity in transfer hydrogenation of carbonyl compounds.

引用

页码：1376 / 1377

页数：2

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