Ion-Exchangeable Titanate Nanotubes with Visible Light Responsive Photocatalytic Activities for Dyes Degradation

被引:5
作者
Li, Xiukai [1 ]
Zhong, Yushu [1 ,2 ]
机构
[1] Jiangsu Univ, Inst Sci, Zhenjiang 212013, Peoples R China
[2] Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Peoples R China
基金
中国国家自然科学基金;
关键词
Titanate Nanotube; Photocatalysis; Visible Light; Dye Degradation; Ion Exchange; LAMELLAR NIOBIC ACID; TRANSITION-METAL; RHODAMINE-B; TIO2; DECOMPOSITION; NIOBATES;
D O I
10.1166/jnn.2014.8983
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Sn2+- and Pb2+-substituted NaHTi3O7 nanotubes were prepared by a hydrothermal synthesis method followed by ion-exchange reaction. The samples were characterized by XRD, SEM, TEM, XPS and UV-visible diffuse reflectance spectroscopy. The photocatalytic activities were investigated for the photodegradation of methylene orange (MO) and methylene blue (MB) under visible light irradiation. The results indicate that Sn2+ and Pb2+ substitutions could have significant impacts on the optical properties and photocatalytic activities of samples. Both Sn2+- and Pb2+-substituted NaHTi3O7 nanotubes show activities for methylene orange and methylene blue photodegradation under visible light irradiation. With better absorption of visible light, the Sn-NaHTi3O7 sample showed higher activity than Pb-NaHTi3O7.
引用
收藏
页码:7151 / 7156
页数:6
相关论文
共 42 条
[1]   Visible-light photocatalysis in nitrogen-doped titanium oxides [J].
Asahi, R ;
Morikawa, T ;
Ohwaki, T ;
Aoki, K ;
Taga, Y .
SCIENCE, 2001, 293 (5528) :269-271
[2]   Energy structure and photocatalytic activity of niobates and tantalates containing Sn(II) with a 5s2 electron configuration [J].
Hosogi, Y ;
Tanabe, K ;
Kato, H ;
Kobayashi, H ;
Kudo, A .
CHEMISTRY LETTERS, 2004, 33 (01) :28-29
[3]   PHOTOCATALYTIC ACTIVITIES OF POTASSIUM-DOPED LEAD NIOBATES AND THE EFFECT OF POLING [J].
INOUE, Y ;
HAYASHI, O ;
SATO, K .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1990, 86 (12) :2277-2282
[4]   Visible-light-response and photocatalytic activities of TiO2 and SrTiO3 photocatalysts codoped with antimony and chromium [J].
Kato, H ;
Kudo, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (19) :5029-5034
[5]   Role of Ag+ in the band structures and photocatalytic properties of AgMO3 (M:: Ta and Nb) with the perovskite structure [J].
Kato, H ;
Kobayashi, H ;
Kudo, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (48) :12441-12447
[6]   A generic method of visible light sensitization for perovskite-related layered oxides: Substitution effect of lead [J].
Kim, HG ;
Becker, OS ;
Jang, JS ;
Ji, SM ;
Borse, PH ;
Lee, JS .
JOURNAL OF SOLID STATE CHEMISTRY, 2006, 179 (04) :1214-1218
[7]   An undoped, single-phase oxide photocatalyst working under visible light [J].
Kim, HG ;
Hwang, DW ;
Lee, JS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (29) :8912-8913
[8]   A novel aqueous process for preparation of crystal form-controlled and highly crystalline BiVO4 powder from layered vanadates at room temperature and its photocatalytic and photophysical properties [J].
Kudo, A ;
Omori, K ;
Kato, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (49) :11459-11467
[9]   Visible-light-driven nitrogen-doped TiO2 photocatalysts:: effect of nitrogen precursors on their photocatalysis for decomposition of gas-phase organic pollutants [J].
Li, D ;
Haneda, H ;
Hishita, S ;
Ohashi, N .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2005, 117 (01) :67-75
[10]   Facile ion-exchanged synthesis of Sn2+ incorporated potassium titanate nanoribbons and their visible-light-responded photocatalytic activity [J].
Li, Qiuye ;
Kako, Tetsuya ;
Ye, Jinhua .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (08) :4716-4723