Reduction in ohmic contact resistance at interface between Gd-doped CeO2 interlayer and Sc2O3-stabilized ZrO2 electrolyte in SOFCs to improve performance

被引：17

作者：

Shimada, Hiroyuki ^{[1
]}

Hagiwara, Akifusa ^{[1
]}

机构：

[1] Tokyo Elect Power Co Ltd, Engn R&D Dept, Tsurumi Ku, Yokohama, Kanagawa 2308510, Japan

来源：

SOLID STATE IONICS | 2014年 / 258卷

关键词：

SOFC; CeO2; ZrO2; Contact resistance; Interlayer; Anode-supported cell; OXIDE FUEL-CELLS; YTTRIA-STABILIZED ZIRCONIA; CATHODE MATERIALS; TEMPERATURE SOFCS; OXYGEN ELECTRODES; CERIA; DENSIFICATION; CERAMICS; LAMNO3;

D O I：

10.1016/j.ssi.2014.01.036

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Influence of the ohmic contact resistance at the interface between Gd-doped CeO2 (GDC) interlayer and scandia-stabilized zirconia (ScSZ) electrolyte on the performance of solid oxide fuel cells (SOFCs) was investigated. When GDC interlayer was used, the ohmic resistance of SOFCs was increased due to insufficient contact conditions between the GDC interlayer and ScSZ electrolyte. To improve the contact conditions, the effect of sintering temperature and sintering aids (Mn, Fe, Bi) on the ohmic contact resistance was evaluated. As a result, using an optimized Mn-modified GDC interlayer (with added 0.3 mol% Mn and sintered at 1300 degrees C) to decrease the ohmic contact resistance, an anode-supported cell with Sr-doped LaFeO3 cathode and ScSZ electrolyte achieved a power density of 1.5 W cm(-2) at 800 degrees C. (c) 2014 Elsevier B.V. All rights reserved.

引用

页码：38 / 44

页数：7

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