N, S Co-Doped Porous Carbon from Antibiotic Bacteria Residues Enables a High-Performance FeF3 . 0.33H2O Cathode for Li-Ion Batteries

被引:14
|
作者
Ding, Jing [1 ]
Zhou, Xiangyang [1 ]
Wang, Qian [1 ]
Luo, Chucheng [1 ]
Yang, Juan [1 ]
Tang, Jingjing [1 ]
机构
[1] Cent South Univ, Sch Met & Environm, Changsha, Hunan, Peoples R China
基金
中国国家自然科学基金;
关键词
Li-ion battery; N; S co-doping; Porous carbon; FeF3  ⋅   0; 33H(2)O cathode; RATE CAPABILITY CATHODE; IRON FLUORIDE; FEF3-CENTER-DOT-0.33H(2)O; NANOCOMPOSITE; STORAGE;
D O I
10.1002/celc.202001353
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
FeF3 . 0.33H(2)O is considered as a potential candidate cathode material owing to the special structure with one-dimension (1D) tunnel. However, its practical application is hindered by the poor electric conductivity. In this work, FeF3 . 0.33H(2)O embedded into N, S co-doped porous carbon (NSPC) derived from antibiotic bacterial residues was synthesized by a facile wet-impregnation method. Close contact of FeF3 . 0.33H(2)O nanoparticles with NSPC can provide the rapid electron conduction channel and keep the structural stability, which endows that FeF3 . 0.33H(2)O@NSPC electrode achieves excellent cycling performance with a reversible capacity of 164.5 mAh g(-1) at 40 mA g(-1) after 100 cycles between 2.0 and 4.5 V and good rate performance. This study offers a new method for high-value utilization of antibiotic bacteria residues (ABRs) for application in energy storage.
引用
收藏
页码:4931 / 4935
页数:5
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