N, S Co-Doped Porous Carbon from Antibiotic Bacteria Residues Enables a High-Performance FeF3 . 0.33H2O Cathode for Li-Ion Batteries

被引：15
作者：
Ding, Jing [1 ]
Zhou, Xiangyang [1 ]
Wang, Qian [1 ]
Luo, Chucheng [1 ]
Yang, Juan [1 ]
Tang, Jingjing [1 ]
机构：
[1] Cent South Univ, Sch Met & Environm, Changsha, Hunan, Peoples R China
来源：
CHEMELECTROCHEM | 2020年 / 7卷 / 24期
基金：
中国国家自然科学基金;
关键词：
Li-ion battery; N; S co-doping; Porous carbon; FeF3  ⋅   0; 33H(2)O cathode; RATE CAPABILITY CATHODE; IRON FLUORIDE; FEF3-CENTER-DOT-0.33H(2)O; NANOCOMPOSITE; STORAGE;
D O I：
10.1002/celc.202001353
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
FeF3 . 0.33H(2)O is considered as a potential candidate cathode material owing to the special structure with one-dimension (1D) tunnel. However, its practical application is hindered by the poor electric conductivity. In this work, FeF3 . 0.33H(2)O embedded into N, S co-doped porous carbon (NSPC) derived from antibiotic bacterial residues was synthesized by a facile wet-impregnation method. Close contact of FeF3 . 0.33H(2)O nanoparticles with NSPC can provide the rapid electron conduction channel and keep the structural stability, which endows that FeF3 . 0.33H(2)O@NSPC electrode achieves excellent cycling performance with a reversible capacity of 164.5 mAh g(-1) at 40 mA g(-1) after 100 cycles between 2.0 and 4.5 V and good rate performance. This study offers a new method for high-value utilization of antibiotic bacteria residues (ABRs) for application in energy storage.
引用
收藏
页码：4931 / 4935
页数：5
相关论文
共 32 条
[1]   Antibiotics and antibiotic resistance in water environments [J].
Baquero, Fernando ;
Martinez, Jose-Luis ;
Canton, Rafael .
CURRENT OPINION IN BIOTECHNOLOGY, 2008, 19 (03) :260-265
[2]   Ammonium Fluoride Mediated Synthesis of Anhydrous Metal Fluoride-Mesoporous Carbon Nanocomposites for High-Performance Lithium Ion Battery Cathodes [J].
Chun, Jinyoung ;
Jo, Changshin ;
Sahgong, Sunhye ;
Klin, Min Gyu ;
Lim, Eunho ;
Kim, Dong Hyeon ;
Hwang, Jongkook ;
Kang, Eunae ;
Ryu, Keun Ah ;
Jung, Yoon Seok ;
Kim, Youngsik ;
Lee, Jinwoo .
ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (51) :35180-35190
[3]   Reversible phase transition enabled by binary Ba and Ti-based surface modification for high voltage LiCoO2 cathode [J].
Hu, Bei ;
Lou, Xiaobing ;
Li, Chao ;
Geng, Fushan ;
Zhao, Chong ;
Wang, Jianyin ;
Shen, Ming ;
Hu, Bingwen .
JOURNAL OF POWER SOURCES, 2019, 438
[4]   N, S co-doped biomass derived carbon with sheet-like microstructures for supercapacitors [J].
Ji, Linlin ;
Wang, Bin ;
Yu, Yanling ;
Wang, Nuoxin ;
Zhao, Jinbao .
ELECTROCHIMICA ACTA, 2020, 331
[5]   Crosslinked MnO2 Nanowires Anchored in Sulfur Self-Doped Porous Carbon Skeleton with Superior Lithium Storage Performance [J].
Jiang, Min ;
Tang, Jingjing ;
Zhou, Xiangyang ;
Zhang, Jiaming ;
Wang, Qian ;
Xu, Herong ;
Yang, Juan .
CHEMELECTROCHEM, 2018, 5 (24) :3913-3917
[6]  
Kong LN, 2020, ELECTROCHIM ACTA, V349
[7]   Confined Iron Fluoride@CMK-3 Nanocomposite as an Ultrahigh Rate Capability Cathode for Li-Ion Batteries [J].
Li, Bingjiang ;
Zhang, Naiqing ;
Sun, Kening .
SMALL, 2014, 10 (10) :2039-2046
[8]   Carbon Nanotube Wiring of Electrodes for High-Rate Lithium Batteries Using an Imidazolium-Based Ionic Liquid Precursor as Dispersant and Binder: A Case Study on Iron Fluoride Nanoparticles [J].
Li, Chilin ;
Gu, Lin ;
Tong, Jianwei ;
Maier, Joachim .
ACS NANO, 2011, 5 (04) :2930-2938
[9]   A Mesoporous Iron-Based Fluoride Cathode of Tunnel Structure for Rechargeable Lithium Batteries [J].
Li, Chilin ;
Gu, Lin ;
Tong, Jianwei ;
Tsukimoto, Susumu ;
Maier, Joachim .
ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (08) :1391-1397
[10]   Low-Temperature Ionic-Liquid-Based Synthesis of Nanostructured Iron-Based Fluoride Cathodes for Lithium Batteries [J].
Li, Chilin ;
Gu, Lin ;
Tsukimoto, Susumu ;
van Aken, Peter A. ;
Maier, Joachim .
ADVANCED MATERIALS, 2010, 22 (33) :3650-+
1234