Influence of the additives in poly(3-hexylthiophene) hole transport layer on the performance of perovskite solar cells

被引:14
作者
Bi, Haibo [1 ]
Zhang, Yang [1 ]
机构
[1] Henan Univ, Dept Phys, Kaifeng 475004, Henan, Peoples R China
关键词
Perovskite solar cells; Poly(3-hexylthiophene); Solar energy materials; Interfaces;
D O I
10.1016/j.matlet.2015.09.092
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The hybrid organic-inorganic methylammonium lead trihalide (CH3NH3PbI3-xCl5) perovskite solar cells employing poly(3-hexylthiophene) (P3HT) hole transport layer with different doped amounts of bis (trifluoromethane) sulfonimide lithium salt (Li-TFSI) and 4-tert-butylpyridine (D-TBP) are fabricated. It is found that the doped amounts of Li-TFSI and D-TBP greatly affect the performance of the devices, such as surface coverage, Hall mobility and bulk concentration of P3HT films. The highest power conversion efficiency of 9.7% is obtained in optimal devices due to the enhanced charge transport and the reduced charge recombination at the interfaces of the devices. The best efficiency of the optimal devices with Li-TFSI and D-TBP is increased by similar to 90%, compared with the reference without additives. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:767 / 769
页数:3
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