Synthesis and crystal structure of [Cd(HO-BDC)(phen)•H2O]n

被引：0
|
作者：
Zhuo Xin
Pan Zhao-Rui
Wang Zuo-Wei
Li Yi-Zhi
Zheng He-Gen [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Suzhou Coll, Photoelect Chem Lab, Suzhou 234000, Anhui, Peoples R China
[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 22卷 / 10期
关键词：
Cd complex; 5-hydroxyisophthalic acid; crystal structure; hydrogen bond; photoluminescence;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel coordination ploymer [Cd(HO-BDC)(phen)center dot H2O], (where HO-BDC is 5-Hydroxylsophthalic acid and phen is 1,10-phenanthroline) has been synthesized and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group P2/c, with a = 0.876 4 (2) nm, b = 1.233 0(3) nm, c = 1.761 2(4) nm, beta = 109.152(9)degrees, V = 1.797 8(7) nm(3), Z = 4, M-r = 490.73, D-c = 1.813 g(.)cm(-3), F(000) = 976, mu = 1.258 mm(-1), the final R = 0.043 8 and wR = 0.098 9 for 2 880 observed reflections with I > 2 sigma (I). The structural analysis shows that the complex has a one-dimensional chain structure. CCDC: 609770.
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页码：1847 / 1851
页数：5
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