Preparation and characterization of the waterborne polyurethane modified with nanosilica

被引:72
作者
Chen, Jing-Jing [1 ]
Zhu, Chuan-Fang [1 ]
Deng, Hong-Tao [1 ]
Qin, Zheng-Ni [1 ]
Bai, Yi-Qiong [1 ]
机构
[1] Cent China Normal Univ, Coll Chem, Wuhan 430079, Peoples R China
关键词
Waterborne polyurethane; Nanosilica; Composite; NANOCOMPOSITE; SILICA;
D O I
10.1007/s10965-008-9238-7
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The nano-SiO2 is used to modify the waterborne polyurethane, and the morphology and performance of the waterborne polyurethane (are studied in) prepared by the insuit polymerization method and the blending method. The properties and structure have been characterized by fourier transform infrared spectra (IR), differential scanning calorimetry (DSC), Thermal gravimetric (TG), transmittance electron microscopy (TEM) and Dynamical Mechanical Analysis (DMA). The experiment results show that, compared with the blending method, the in-suit polymerization has more advantages in that the nano-SiO2 is evenly dispersed in the waterborne polyurethane, obviously in microphase separation and better in resistance to high temperature and water.
引用
收藏
页码:375 / 380
页数:6
相关论文
共 17 条
[1]   Synthesis and characterization of novel segmented polyurethane/clay nanocomposites [J].
Chen, TK ;
Tien, YI ;
Wei, KH .
POLYMER, 2000, 41 (04) :1345-1353
[2]   Preparation and characterization of nanocomposite polyurethane [J].
Chen, YC ;
Zhou, SX ;
Yang, HH ;
Gu, GX ;
Wu, LM .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2004, 279 (02) :370-378
[3]  
CONG SF, 2003, POLYURETHANE COATING, P288
[4]   The effects of altered reaction conditions on the properties of anionic poly(urethane-urea) dispersions and films cast from the dispersions [J].
Harjunalanen, T ;
Lahtinen, M .
EUROPEAN POLYMER JOURNAL, 2003, 39 (04) :817-824
[5]  
HOU MH, 2005, YINGYONG HUAXUECHIN, V22, P1132
[6]  
HOU MH, 2005, SHIYOU HUAGONGCHIN, V34, P677
[7]   Surfactant-free emulsions for waterborne, two-component polyurethane coatings [J].
Huybrechts, J ;
Bruylants, P ;
Vaes, A ;
De Marre, A .
PROGRESS IN ORGANIC COATINGS, 2000, 38 (02) :67-77
[8]   Properties of waterborne polyurethanes based on polycarbonate diol reinforced with organophilic clay [J].
Jeong, HM ;
Jang, KH ;
Cho, KW .
JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, 2003, B42 (06) :1249-1263
[9]   Preparation of, the hydrophilic/hydrophobic silica particles [J].
Jesionowski, T ;
Krysztafkiewicz, A .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2002, 207 (1-3) :49-58
[10]   Synthesis and characterization of polysilicic acid nanoparticles/waterborne polyurethane nanocomposite [J].
Kuan, HC ;
Su, HY ;
Ma, CCM .
JOURNAL OF MATERIALS SCIENCE, 2005, 40 (23) :6063-6070