Di-μ-chloro-bis[chloro(phenyl 2-pyridyl ketone oxime-κ2N,N′)copper(II)]

被引:7
作者
Xiang, Jing [1 ]
Li, Qin [1 ]
Mei, Ping [1 ]
机构
[1] Yangtze Univ, Coll Chem & Environm Engn, Jinzhou 434020, Hubei, Peoples R China
关键词
D O I
10.1107/S1600536806033836
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title complex, [Cu2Cl4(C12H10N2O)(2)], was synthesized by reacting phenyl 2-pyridyl ketone oxime with CuCl(2)(.)2H(2)O in a basic medium. The organic ligand coordinates to the Cu-II ions through its N atoms, while the oxime O atom remains uncoordinated. The Cl- ions play two roles: one is a terminal ligand and the other is a bridging ligand, the bridge being formed through a crystallographic inversion centre.
引用
收藏
页码:M2348 / M2349
页数:2
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