Synthesis and crystal structure of the cryptate complex [Gd(L)(DMF)]center dot KSCN center dot CH3CN center dot 3H(2)O (L is a deprotonated phenol-based N8O3 cryptand)

被引：17

作者：

Yu, SY

Wang, QM

Wu, B

Wu, XT

Hu, HM

Wang, LF

Wu, AX

机构：

[1] CHINESE ACAD SCI,FUJIAN INST RES STRUCT MATTER,STATE KEY LAB STRUCT CHEM,FUZHOU 350002,FUJIAN,PEOPLES R CHINA

[2] NANJING UNIV,STATE KEY LAB COORDINAT CHEM,NANJING 210093,PEOPLES R CHINA

[3] LANZHOU UNIV,DEPT CHEM,LANZHOU 730000,PEOPLES R CHINA

来源：

POLYHEDRON | 1997年 / 16卷 / 02期

关键词：

gadolinium; cryptate; complex; cryptand; synthesis; structure;

D O I：

10.1016/0277-5387(96)00237-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cryptate complex [Gd(L)(DMF)]. KSCN . CH3CN . 3H(2)O has been synthesized by the reaction of gadolinium isothiocyanate and potassium thiocyanate with cryptate [Na(H(2)L)], which was prepared by a (2+3) Schiff-base condensation of tris(2-aminoethyl)amine and 2,6-diformyl-4-methoxyphenol in the presence of NaOH. The Gd atom is encapsulated in the cryptand with an unsymmetric eight-coordinate environment. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：321 / 325

页数：5

共 17 条

[1] DESIGN AND SYNTHESIS OF MACROCYCLIC LIGANDS AND THEIR COMPLEXES OF LANTHANIDES AND ACTINIDES [J].