Fire retardancy of bis[2-(methacryloyloxy)ethyl] phosphate modified poly(methyl methacrylate) nanocomposites containing layered double hydroxide and montmorillonite

被引：29

作者：

Wang, Linjiang ^{[1
,2
,3
]}

Su, Shengpei ^{[4
]}

Chen, Dan ^{[4
]}

Wilkie, Charles A. ^{[1
,2
]}

机构：

[1] Marquette Univ, Dept Chem, Milwaukee, WI 53201 USA

[2] Marquette Univ, Fire Retardant Res Facil, Milwaukee, WI 53201 USA

[3] Guilin Univ Technol, Dept Chem & Mat Engn, Guilin 541004, Peoples R China

[4] Hunan Normal Univ, Dept Chem & Chem Engn, Changsha 410081, Hunan, Peoples R China

来源：

POLYMER DEGRADATION AND STABILITY | 2009年 / 94卷 / 07期

关键词：

Nanocomposites; Layered double hydroxides; PMMA; Fire retardancy; RIGID POLYURETHANE FOAMS; CLAY NANOCOMPOSITES; THERMAL-DEGRADATION; PHOSPHORUS; POLYSTYRENE; PMMA;

D O I：

10.1016/j.polymdegradstab.2009.03.022

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Copolymer nanocomposites were prepared by suspension copolymerization of bis[2-(methacryloyloxy)ethyl] phosphate and methyl methacrylate, together with bis(2-ethylhexyl) phosphate layered double hydroxide and a montmorillonite, Cloisite 93A. X-ray diffraction and transmission electron microscopy were used to characterize the morphology of nanocomposites and the dispersion of additives in the polymer. The thermal stability of the nanocomposites has been assessed by thermogravimetric analysis and cone calorimetry has been used to study the fire properties. Bis[2-(methacryloyloxy)ethyl] phosphate not only copolymerized with MMA, but also aids in the dispersion of additives in PMMA. The copolymer nanocomposites have better dispersion and higher degradation temperature and more char mass than the corresponding PMMA nanocomposites. The largest peak reduction in the heat release rate of the copolymer nanocomposites are 52 and 65% for LDH and MMT additives, respectively. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：1110 / 1118

页数：9

共 31 条

[1] Synthesis and formulation of novel phosphorylated dame retardant curatives for thermoset resins [J].

Buckingham, MR ;

Lindsay, AJ ;

Stevenson, DE ;

Muller, G ;

Morel, E ;

Costes, B ;

Henry, Y .

POLYMER DEGRADATION AND STABILITY, 1996, 54 (2-3) :311-315

[2] The influence of carbon nanotubes, organically modified montmorillonites and layered double hydroxides on the thermal degradation and fire retardancy of polyethylene, ethylene-vinyl acetate copolymer and polystyrene [J].

Costache, Marius C. ;

Heidecker, Matthew J. ;

Manias, E. ;

Camino, Giovanni ;

Frache, Alberto ;

Beyer, Gunter ;

Gupta, Rakesh K. ;

Wilkie, Charles A. .

POLYMER, 2007, 48 (22) :6532-6545

[3] PHOSPHINE OXIDE CONTAINING AROMATIC POLYESTER [J].

DELAVIZ, Y ;

GUNGOR, A ;

MCGRATH, JE ;

GIBSON, HW .

POLYMER, 1992, 33 (24) :5346-5347

[4] Flame retardance in some polystyrenes and poly(methyl methacrylate)s with covalently bound phosphorus-containing groups: initial screening experiments and some laser pyrolysis mechanistic studies [J].

Ebdon, JR ;

Price, D ;

Hunt, BJ ;

Joseph, P ;

Gao, FG ;

Milnes, GJ ;

Cunliffe, LK .

POLYMER DEGRADATION AND STABILITY, 2000, 69 (03) :267-277

[5] A study of structural memory effects in synthetic hydrotalcites using environmental SEM [J].

Erickson, KL ;

Bostrom, TE ;

Frost, RL .

MATERIALS LETTERS, 2005, 59 (2-3) :226-229

[6]

GILMAN JW, 2007, J PHYS CHEM B, V111, P12685

[7] A review of phosphorus-containing flame retardants [J].

Green, J .

JOURNAL OF FIRE SCIENCES, 1996, 14 (05) :353-366

[8]

Green J., 2000, FIRE RETARDANCY POLY, P147

[9] The effect of polymerisation conditions on the kinetics and mechanisms of thermal degradation of PMMA [J].

Holland, BJ ;

Hay, JN .

POLYMER DEGRADATION AND STABILITY, 2002, 77 (03) :435-439

[10]

Hu Y., 2007, FLAME RETARDANT POLY, P191

← 1 2 3 4 →