Isomerism of assembled iron complex bridged by 1,2-di(4-pyridyl)ethane and its solid-to-solid transformation accompanied by a change of electronic state

被引：24
|
作者：
Morita, Takaki
Asada, Yoritaka
Okuda, Tsutomu
Nakashima, Satoru
机构：
[1] Hiroshima Univ, Nat Sci Ctr Basic Res & Dev N BARD, Higashihiroshima 7398526, Japan
[2] Hiroshima Univ, Dept Chem, Grad Sch Sci, Higashihiroshima 7398526, Japan
[3] Hiroshima Kokusai Gakuin Univ, Dept Biorecycling, Fac Engn, Aki Ku, Hiroshima 7390321, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2006年 / 79卷 / 05期
关键词：
D O I：
10.1246/bcsj.79.738
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three supramolecular isomers of an Fe-NCS complex and two isomers of an Fe-NCSe complex bridged by 1,2-di(4-pyridyl)ethane have been obtained. Fe-57 Mossbauer spectroscopy revealed a drastic change in the QS value by changing the structure and by changing NCS to NCSe. Solid-to-solid transformation was observed, accompanied by a drastic change in the QS value.
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收藏
页码：738 / 744
页数：7
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