Synthesis and luminescent properties of UV-excited thermal stable red-emitting phosphor Ba3Lu(PO4)3: Eu3+ for NUV LED

被引:87
作者
Zhang, Xinguo [1 ,2 ]
Zhang, Jilin [3 ]
Gong, Menglian [2 ]
机构
[1] Guangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R China
[2] Sun Yat Sen Univ, Sch Chem & Chem Engn, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Guangdong, Peoples R China
[3] Hunan Normal Univ, Coll Chem & Chem Engn, Changsha 410081, Hunan, Peoples R China
关键词
Luminescence; Ba3Lu(PO4)(3); Eu3+; Phosphor; NUV LED; PHOTOLUMINESCENCE PROPERTIES; ENERGY-TRANSFER;
D O I
10.1016/j.optmat.2013.12.024
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A series of Ba3Lu(PO4)(3): Eu3+ phosphors were synthesized by high-temperature solid-state method, and their UV-vis luminescent properties were investigated. The f-f transitions of Eu3+ in the host lattice were assigned and discussed. The excitation and emission spectra indicate that this phosphor can be excited by near ultraviolet (NUV) light, and exhibits strong red emission. The concentration quenching on Eu3+ emission and its mechanism were investigated. This phosphor shows a good thermal stability at high temperature (similar to 180 degrees C). The fabricated prototype LEDs with Ba3Lu(PO4)(3): Eu3+ and 395 nm-emitting InGaN chips exhibit bright red emission. The present study suggests that Ba3Lu(PO4)(3): Eu3+ can be a potential red phosphor for NUV light-emitting diodes. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:850 / 853
页数:4
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