3-Ethynyl-2,2,5,5-tetramethyl-1-oxyl-3-pyrroline

被引：2
|
作者：
Frolow, Olga [1 ]
Bats, Jan W. [1 ]
Engels, Joachim W. [1 ]
机构：
[1] Goethe Univ Frankfurt, Inst Organ Chem, D-60438 Frankfurt, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
D O I：
10.1107/S1600536809026725
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The five-membered ring of the title compound, C10H14NO, is almost planar [mean deviation from best plane = 0.006 (1) angstrom]. The N-O bond is in the plane of the five-membered ring. The molecule is positioned about a pseudo-mirror plane at y = 0.375. In the crystal, molecules are connected by intermolecular C-H center dot center dot center dot O contacts into layers parallel to (010).
引用
收藏
页码：O1848 / U2891
页数：9
相关论文
共 50 条
  • [21] Synthesis and crystal structure of a pyrroline nitroxide radical, (N-2,2,5,5-tetramethyl-1-oxo-3-pyrroline-3-carbonyl) (N,N′-diisopropyl)urea
    Chen, SY
    Nie, JJ
    You, JZ
    Xu, DJ
    Chen, YZ
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2001, 31 (06) : 339 - 343
  • [22] Synthesis and crystal structure of a pyrroline nitroxide radical, (N-2,2,5,5-tetramethyl-1-oxo-3-pyrroline-3-carbonyl) (N,N′-diisopropyl)urea
    Shao-Yuan Chen
    Jing-Jing Nie
    Jin-Zhong You
    Duan-Jun Xu
    Yao-Zu Chen
    Journal of Chemical Crystallography, 2001, 31 : 339 - 343
  • [23] 5-[4′-(2,2,5,5-Tetramethyl-3-pyrroline-1-oxyl-3-carbonyl)biphenyl-4-ylethynyl]-2,3,7,8,12,13,17,18-octaethylporphyrinato}copper(II) benzene solvate
    Bolte, Michael
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : M1609 - M1610
  • [24] ELECTROCHEMICAL REDUCTION OF THE COMPLEX OF ZN(II) WITH 4-(2'-OXOPROPYLIDENE)-2,2,5,5-TETRAMETHYL-3-IMIDAZOLIDINE-1-OXYL
    YANILKIN, VV
    KADIROV, MK
    KARGIN, YM
    ILYASOV, AV
    MOROZOV, VI
    LARIONOV, SV
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1991, 40 (01): : 43 - 47
  • [25] HALOGEN-CONTAINING NITROXYL RADICALS .5. THE SYNTHESIS AND REACTIONS OF 2,2,5,5-TETRAMETHYL-DELTA-3-PYRROLIN-1-OXYL
    CHUDINOV, AV
    ROZANTSEV, EG
    ROZYNOV, BV
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1983, 32 (02): : 370 - 375
  • [26] An efficient synthesis of 3-(N-piperidinemethyl)-2,2,5,5-tetramethyl-1-oxy-3-pyrroline, a promising radioprotector for cancer radiotherapy
    Wu, Haitao
    Coble, Vincent
    Vasalatiy, Olga
    Swenson, Rolf E.
    Krishna, Murali C.
    Mitchell, James B.
    TETRAHEDRON LETTERS, 2014, 55 (40) : 5570 - 5571
  • [27] STRUCTURE OF 2,2,5,5-TETRAMETHYL-3-PHENYLETHYNYL-3-PYRROLIDINOL
    CYGLER, M
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 1981, 37 (SEP) : 1765 - 1767
  • [28] 4-HYDROXYIMINONITROMETHYL-2,2,5,5-TETRAMETHYL-3-IMIDAZOLINE-1-OXYL AS A PRECURSOR OF SPIN-LABELED NITRILE OXIDE
    REZNIKOV, VA
    VOLODARSKY, LB
    RUSSIAN CHEMICAL BULLETIN, 1994, 43 (02) : 269 - 271
  • [29] Crystal and molecular structure of 3-(N-Methoxy-N-methylcarbamoyl)- 2,2,5,5-tetramethyl-1-oxy-pyrroline
    Department für Chemie, Lehrstuhl für Anorganische Chemie, Technische Universität München, Lichtenbergstraße 4, 85747 Garching, Germany
    Z. Naturforsch. Sect. B J. Chem. Sci., 4 (475-478):
  • [30] Crystal and Molecular Structure of 3-(N-Methoxy-N-methylcarbamoyl)-2,2,5,5-tetramethyl-1-oxy-pyrroline
    Frey, Guido D.
    Herdtweck, Eberhardt
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2010, 65 (04): : 475 - 478
12345