A metal-organic framework supported iridium catalyst for the gas phase hydrogenation of ethylene

被引：21

作者：

Perlata, Ricardo A. ^{[1
,2
]}

Huxley, Michael T. ^{[1
,2
]}

Shi, Zhaolin ^{[3
]}

Zhang, Yue-Biao ^{[3
]}

Sumby, Christopher J. ^{[1
,2
]}

Doonan, Christian J. ^{[1
,2
]}

机构：

[1] Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia

[2] Univ Adelaide, Ctr Adv Nanomat, Adelaide, SA 5005, Australia

[3] ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 97期

基金：

澳大利亚研究理事会;

关键词：

SINGLE-CRYSTAL; DECARBONYLATION; COMPLEXES; CHEMISTRY; ZEOLITE; SITE; IR;

D O I：

10.1039/d0cc06058e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mutable structures of metal-organic frameworks (MOFs) allow their use as novel supports for transition metal catalysts. Herein we prepare an iridium bis(ethylene) catalyst bound to the neutral N-donors of a MOF structure and show that the compound is a stable gas phase ethylene hydrogenation catalyst. The data illustrate the need to carefully consider the inner sphere (support) and outer sphere (anion) chemistry.

引用

页码：15313 / 15316

页数：4

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