A metal-organic framework supported iridium catalyst for the gas phase hydrogenation of ethylene

被引：19
|
作者：
Perlata, Ricardo A. [1 ,2 ]
Huxley, Michael T. [1 ,2 ]
Shi, Zhaolin [3 ]
Zhang, Yue-Biao [3 ]
Sumby, Christopher J. [1 ,2 ]
Doonan, Christian J. [1 ,2 ]
机构：
[1] Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia
[2] Univ Adelaide, Ctr Adv Nanomat, Adelaide, SA 5005, Australia
[3] ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 97期
基金：
澳大利亚研究理事会;
关键词：
SINGLE-CRYSTAL; DECARBONYLATION; COMPLEXES; CHEMISTRY; ZEOLITE; SITE; IR;
D O I：
10.1039/d0cc06058e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The mutable structures of metal-organic frameworks (MOFs) allow their use as novel supports for transition metal catalysts. Herein we prepare an iridium bis(ethylene) catalyst bound to the neutral N-donors of a MOF structure and show that the compound is a stable gas phase ethylene hydrogenation catalyst. The data illustrate the need to carefully consider the inner sphere (support) and outer sphere (anion) chemistry.
引用
收藏
页码：15313 / 15316
页数：4
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