Excess molar enthalpy, density, and speed of sound for the mixtures β-pinene plus 1- or 2-pentanol at (283.15, 298.15, and 313.15) K

被引：42
作者：
Ribeiro, Ana Francisca [1 ]
Langa, Elisa [1 ]
Mainar, Ana M. [1 ]
Pardo, Juan I. [1 ]
Urieta, Jose S. [1 ]
机构：
[1] Univ Zaragoza, Grp Appl Thermodynam & Surfaces GATHERS, Aragon Inst Engn Res 13A, Fac Ciencias, E-50009 Zaragoza, Spain
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2006年 / 51卷 / 05期
关键词：
D O I：
10.1021/je060210c
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Excess molar enthalpies, densities, and speeds of sound at the temperatures (283.15, 298.15, 313.15) K are reported for the binary mixtures 6,6-dimethyl-2-methylenebicyclo[3.1.1]heptane (beta-pinene) + 1-pentanol and beta-pinene + 2-pentanol. Excess molar volumes, speed of sound deviations, isentropic compressibilities, and excess isentropic compressibilities have been calculated from the densities and speeds of sound. The excess properties and property deviations have been fitted to either Redlich-Kister polynomials or Pade approximants to reproduce the experimental data as accurately as possible. Excess properties are positive for both mixtures, while speed of sound deviations show negative values. The values of these properties are discussed in terms of the molecular interactions.
引用
收藏
页码：1846 / 1851
页数：6
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