Robust nickel-polymer nanocomposite particles for hydrogen generation from sodium borohydride

被引:29
作者
Cai, Haokun [1 ,2 ]
Lu, Ping [1 ]
Dong, Jian [1 ]
机构
[1] Shaoxing Univ, Sch Chem & Chem Engn, Shaoxing 312000, Zhejiang, Peoples R China
[2] Ningbo Univ, Sch Mat Sci & Chem Engn, Ningbo 315211, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
Hydrogen fuel; Nanocomposites; Polymer; Nickel; HYDROLYSIS; CATALYST; NANOCLUSTERS; NABH4; CO; NANOPARTICLES; DEPOSITION; STORAGE;
D O I
10.1016/j.fuel.2015.11.011
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Two types of polymer nanocomposite particles were developed through electroless plating of nickel onto polymer nanospheres for hydrogen production from sodium borohydride solution. Different distributions of Ni in the polymer particles can be obtained either in polymer core-metal shell morphology or homogeneously hybridized morphology, depending on the hydrophilicity of the polymers. The Ni-polymer particles exhibited high catalytic activities in hydrogen production reactions with excellent recyclability, which is important in portable clean energy generation technology. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:297 / 301
页数:5
相关论文
共 32 条
[1]   An ultrasafe hydrogen generator: aqueous, alkaline borohydride solutions and Ru catalyst [J].
Amendola, SC ;
Sharp-Goldman, SL ;
Janjua, MS ;
Kelly, MT ;
Petillo, PJ ;
Binder, M .
JOURNAL OF POWER SOURCES, 2000, 85 (02) :186-189
[2]   Amorphous Ni-B hollow spheres synthesized by controlled organization of Ni-B nanoparticles over PS beads via surface seeding/electroless plating [J].
Chen, XY ;
Yang, WL ;
Wang, S ;
Qiao, MH ;
Yan, SR ;
Fan, KN ;
He, HY .
NEW JOURNAL OF CHEMISTRY, 2005, 29 (02) :266-268
[3]   A facial microwave-assisted polyol activation process for fabrication of Ni@PMMA microspheres [J].
Chen, Yen-Chung ;
Liu, Robert Lian-Huey ;
Chang, Chang-Pin ;
Chen, Xin-Liang ;
Shu, Hsiou-Jeng ;
Ger, Ming-Der .
MATERIALS RESEARCH BULLETIN, 2011, 46 (08) :1163-1167
[4]   Preparation of polyvinylidene fluoride-nickel hollow fiber catalytic membranes for hydrogen generation from sodium borohydride [J].
Chen, Yingbo ;
Shi, Yang ;
Liu, Xiaojing ;
Zhang, Yufeng .
FUEL, 2015, 140 :685-692
[5]   Water soluble polymer stabilized iron(0) nanoclusters: A cost-effective and magnetically recoverable catalyst in hydrogen generation from the hydrolysis of sodium borohydride and ammonia borane [J].
Dinc, Melek ;
Metin, Onder ;
Ozkar, Saim .
CATALYSIS TODAY, 2012, 183 (01) :10-16
[6]   Electroless nickel plating on polymer particles [J].
Fujii, Syuji ;
Hamasaki, Hiroyuki ;
Takeoka, Hiroaki ;
Tsuruoka, Takaaki ;
Akamatsu, Kensuke ;
Nakamura, Yoshinobu .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2014, 430 :47-55
[7]   Regio- and Chemoselective Reduction of Nitroarenes and Carbonyl Compounds over Recyclable Magnetic Ferrite-Nickel Nanoparticles (Fe3O4-Ni) by Using Glycerol as a Hydrogen Source [J].
Gawande, Manoj B. ;
Rathi, Anuj K. ;
Branco, Paula S. ;
Nogueira, Isabel D. ;
Velhinho, Alexandre ;
Shrikhande, Janhavi J. ;
Indulkar, Utkarsha U. ;
Jayaram, Radha V. ;
Ghumman, C. Amjad A. ;
Bundaleski, Nenad ;
Teodoro, Orlando M. N. D. .
CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (40) :12628-12632
[8]  
Jeon KJ, 2011, NAT MATER, V10, P286, DOI [10.1038/NMAT2978, 10.1038/nmat2978]
[9]   HYDROGEN GENERATION BY HYDROLYSIS OF SODIUM TETRAHYDROBORATE - EFFECTS OF ACIDS AND TRANSITION-METALS AND THEIR SALTS [J].
KAUFMAN, CM ;
SEN, B .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (02) :307-313
[10]   A structured Co-B catalyst for hydrogen extraction from NaBH4 solution [J].
Lee, Jaeyoung ;
Kong, Kyung Yong ;
Jung, Chang Ryul ;
Cho, Eunae ;
Yoon, Sung Pil ;
Han, Jonghee ;
Lee, Tai-Gyu ;
Nam, Suk Woo .
CATALYSIS TODAY, 2007, 120 (3-4) :305-310