Surprising catalytic activity of bismuth (III) triflate in the Friedel-Crafts acylation reaction

被引：161
|
作者：
Desmurs, JR [1 ]
Labrouillere, M [1 ]
LeRoux, C [1 ]
Gaspard, H [1 ]
Laporterie, A [1 ]
Dubac, J [1 ]
机构：
[1] UNIV TOULOUSE 3,LAB ASSOCIE CNRS,F-31062 TOULOUSE,FRANCE
来源：
TETRAHEDRON LETTERS | 1997年 / 38卷 / 51期
关键词：
D O I：
10.1016/S0040-4039(97)10401-4
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Bismuth tris-trifluoromethanesulfonate (Bi(OTf)(3)) was found to be a novel catalyst for the Friedel-Crafts acylation. The reactions of activated or deactivated benzenes such as fluorobenzene proceeded in high yields in the presence of a catalytic amount of BI(OTf)(3). This catalyst is water stable and its catalytic activity is much higher than the one of the other metallic triflates M(OTf)(3) previously reported (M = Al, Ga, Ln or Sc). (C) 1997 Elsevier Science Ltd.
引用
收藏
页码：8871 / 8874
页数：4
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