Triazaheterocyclic compound as an efficient catalyst for dehydration of fructose into 5-hydroxymethylfurfural

被引：13

作者：

Huang, Zhen ^{[1
,2
]}

Pan, Yuanjia ^{[2
,3
]}

Chao, Yimin ^{[4
]}

Shen, Wei ^{[1
,2
]}

Wang, Changchun ^{[2
,3
]}

Xu, Hualong ^{[1
,2
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China

[2] Fudan Univ, Adv Mat Lab, Shanghai 200433, Peoples R China

[3] Fudan Univ, State Key Lab Mol Engn Polymers, Dept Macromol Sci, Shanghai 200433, Peoples R China

[4] Univ E Anglia, Energy Mat Lab, Sch Chem, Norwich NR4 7TJ, Norfolk, England

来源：

RSC ADVANCES | 2014年 / 4卷 / 26期

关键词：

IONIC LIQUIDS; BECKMANN REARRANGEMENT; CONVERSION; BIOMASS; CHEMICALS; HYDROLYSIS; CELLULOSE; GLUCOSE; SUGARS;

D O I：

10.1039/c4ra00534a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hexachlorocyclotriphosphazene and cyanuric chloride are found to be high efficient homogeneous catalysts for dehydration of fructose into 5-hydroxymethylfurfural under mild conditions. The P-Cl or C-Cl bonds play important roles in the reaction, and the strong interaction between the fructose and the electron-withdrawing substituent will help to promote the dehydration.

引用

页码：13434 / 13437

页数：4

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