Triazaheterocyclic compound as an efficient catalyst for dehydration of fructose into 5-hydroxymethylfurfural

被引：13
|
作者：
Huang, Zhen [1 ,2 ]
Pan, Yuanjia [2 ,3 ]
Chao, Yimin [4 ]
Shen, Wei [1 ,2 ]
Wang, Changchun [2 ,3 ]
Xu, Hualong [1 ,2 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
[2] Fudan Univ, Adv Mat Lab, Shanghai 200433, Peoples R China
[3] Fudan Univ, State Key Lab Mol Engn Polymers, Dept Macromol Sci, Shanghai 200433, Peoples R China
[4] Univ E Anglia, Energy Mat Lab, Sch Chem, Norwich NR4 7TJ, Norfolk, England
来源：
RSC ADVANCES | 2014年 / 4卷 / 26期
关键词：
IONIC LIQUIDS; BECKMANN REARRANGEMENT; CONVERSION; BIOMASS; CHEMICALS; HYDROLYSIS; CELLULOSE; GLUCOSE; SUGARS;
D O I：
10.1039/c4ra00534a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hexachlorocyclotriphosphazene and cyanuric chloride are found to be high efficient homogeneous catalysts for dehydration of fructose into 5-hydroxymethylfurfural under mild conditions. The P-Cl or C-Cl bonds play important roles in the reaction, and the strong interaction between the fructose and the electron-withdrawing substituent will help to promote the dehydration.
引用
收藏
页码：13434 / 13437
页数：4
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