Effect of surface hydrophobicity on short-range hydrophobic attraction between silanated silica surfaces

被引:13
作者
Soga, Yuhei [1 ]
Imanaka, Hiroyuki [1 ]
Imamura, Koreyoshi [1 ]
Ishida, Naoyuki [1 ]
机构
[1] Okayama Univ, Dept Appl Chem & Biotechnol, Kita Ku, Okayama 7008530, Japan
基金
日本学术振兴会;
关键词
Hydrophobic attraction; Nanobubble; Silanated surface; Atomic force microscopy; Long-range interaction force; LONG-RANGE; FORCES; BUBBLES; WATER; GAS;
D O I
10.1016/j.apt.2015.10.017
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The interaction forces between silanated silica surfaces without nanobubbles were measured using colloidal probe atomic force microscopy (AFM). To obtain hydrophobic surfaces without nanobubbles, an aqueous solution was introduced between the surfaces following an exchange process involving several solvents. In the obtained approaching force curves, an attractive force was observed from a distance of 10-20 nm, which is an additional attractive force stronger than typical van der Waals attractions. When the surface hydrophobicity decreased, the range of this attraction decreased slightly; the attraction disappeared when the surface contact angle was below 90 degrees. In contrast, measurements in the water-ethanol mixtures revealed that the attraction persisted even when the contact angle was well below 90 degrees. The possible origin of this force was discussed on the basis of the obtained results. (C) 2015 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan.
引用
收藏
页码:1729 / 1733
页数:5
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