All-Conjugated, Rod-Rod Block Copolymers-Generation and Self-Assembly Properties

被引:83
|
作者
Scherf, Ullrich [1 ]
Adamczyk, Sylwia
Gutacker, Andrea
Koenen, Nils
机构
[1] Berg Univ Wuppertal, Macromol Chem Grp, D-42097 Wuppertal, Germany
关键词
block copolymers; conjugated polymers; nanostructures; self-assembly; vesicles; CATALYST-TRANSFER POLYCONDENSATION; CHAIN-GROWTH POLYMERIZATION; POLY(P-PHENYLENE); MECHANISM;
D O I
10.1002/marc.200900088
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Based on their rigid-rod structure all-conjugated, rod-rod block copolymers show a preferred tendency to self-assemble into low-curvature vesicular or lamellar nanostructures independent from their specific chemical structure and composition. This unique and attractive behaviour is clearly illustrated in a few examples of such all-conjugated block copolymers. The resulting nanostructured heteromaterials may find applications in electronic devices or artificial membranes.
引用
收藏
页码:1059 / 1065
页数:7
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