Thermal behavior of some new complexes bearing ligands with polymerisable groups

被引：13

作者：

Badea, M.

Olar, R.

Marinescu, D.

Vasile, G.

机构：

[1] Univ Bucharest, Fac Chem, Dept Inorgan Chem, Bucharest 050663, Romania

[2] Univ Agronom Sci & Vet Med, Dept Agrochem, Bucharest, Romania

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2006年 / 85卷 / 02期

关键词：

acrylate; complexes; formate; thermal stability;

D O I：

10.1007/s10973-005-7176-8

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

This paper reports the investigation of the thermal stability of a series of new complexes with mixed ligands of the type M(dipy)(C3H3O2)(2)(H2O)y ((1) M: Mn, y=1; (2) M: Ni, y=2; (3) M: Cu, y=1; (4) M. Zn, y=2; dipy: 2,2'-dipyridine and C3H3O2 is acrylate anion). The thermal behaviour steps were investigated. The thermal transformations are complex processes according to TG and DTG curves including dehydration, oxidative condensation of acrylate and thermolysis processes. The final products of decomposition are the most stable metal oxides.

引用

收藏

页码：285 / 288

页数：4

相关论文

共 14 条

[1] Thermal behavior of some new chromium complexes with potential biological importance [J].

Badea, M ;

Olar, R ;

Vasile, G ;

Emandi, A ;

Pop, V ;

Marinescu, D .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2005, 81 (02) :273-276

[2] Some new acrylate complexes as a criterion in their selection for further co-polymerization reaction [J].

Badea, M ;

Olar, R ;

Marinescu, D ;

Vasile, G .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2005, 80 (03) :683-685

[3]

BADEA M, 2004, NONLINEAR OPTICS QUA, V32, P100

[4]

BADEA M, IN PRESS J INORG BIO

[5] Binding of transition metal ions [cobalt, copper, nickel and zinc] with furanyl-, thiophenyl-, pyrrolyl-, salicylyl- and pyridyl-derived cephalexins as potent antibacterial agents [J].

Chohan, ZH ;

Pervez, H ;

Khan, KM ;

Rauf, A ;

Supuran, CT .

JOURNAL OF ENZYME INHIBITION AND MEDICINAL CHEMISTRY, 2004, 19 (01) :51-56

[6] Unsymmetrical 1,1′-disubstituted ferrocenes:: Synthesis of Co(ii), Cu(ii), Ni(ii) and Zn(ii) chelates of ferrocenyl-1-thiadiazolo-1′-tetrazole,-1-thiadiazolo-1′-triazole and-1-tetrazolo-1′-triazole with antimicrobial properties [J].

Chohan, ZH ;

Scozzafava, A ;

Supuran, CT .

JOURNAL OF ENZYME INHIBITION AND MEDICINAL CHEMISTRY, 2002, 17 (04) :261-266

[7] Biomedical application of functional polymers (vol 39, pg 99, 1999) [J].

Jagur-Grodzinski, J .

REACTIVE & FUNCTIONAL POLYMERS, 1999, 40 (02) :185-185

[8] Controlling gene expression by zinc(II)-macrocyclic tetraamine complexes [J].

Kikuta, E ;

Koike, T ;

Kimura, E .

JOURNAL OF INORGANIC BIOCHEMISTRY, 2000, 79 (1-4) :253-259

[9] Thermal analysis of polymer-silicate nanocomposites [J].

Kotsilkova, R ;

Petkova, V ;

Pelovski, Y .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2001, 64 (02) :591-598

[10]

Pomogailo A. S., 2001, ADV MAT SCI, V1, P19