Synthesis and crystal structure of trans*-[PtenPyNO2Cl2*](NO3)

被引:0
作者
Koz'min, PA [1 ]
Surazhskaya, MD [1 ]
Chel'tsov-Bebutov, PA [1 ]
机构
[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia
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中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
X-Ray diffraction analysis of the [PtenPyNO(2)Cl(2)](NO3) crystals was carried out (space group P2(1)/c, a = 8.252(1) Angstrom, b = 8.948(1) Angstrom, c= 19.942(2) Angstrom, beta = 96.06(1degrees), V= 1464.3(5) Angstrom(3), Z = 4: 1646 reflections, R-hkl = 0.21). In the complex, the Pt-N(en) bond trans to the shorter Pt-N(Py) bond is shorter than that trans to the longer Pt-N(NO2) bond.
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页码:803 / 805
页数:3
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  • [1] CHERNYAEV II, 1928, IZV I IZUCHENIYU PLA, P85