Free radical copolymerization and kinetic treatment of styrene with N-phenylmaleimide

被引：0

作者：

Shan, GR ^{[1
]}

Weng, ZX ^{[1
]}

Huang, ZM ^{[1
]}

Pan, ZR ^{[1
]}

机构：

[1] ZHEJIANG UNIV,INST POLYMER SCI & ENGN,HANGZHOU 310027,PEOPLES R CHINA

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1997年 / 63卷 / 12期

关键词：

styrene; N-phenylmaleimide; kinetic treatment;

D O I：

10.1002/(SICI)1097-4628(19970321)63:123.0.CO;2-P

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The copolymerization of styrene (M(1)) with N-phenylmaleimide (M(2)) in chloroform with 2,2'-azobis(isobutyronitrile) as an initiator was investigated. The kinetic parameters, such as reactivity ratios, overall activity energy, and the effect of molar fraction of monomers on the initial copolymerization rate, were determined. The bimolecular termination of the copolymerization was proved. The treatment method proposed by Yoshimura and colleagues was used to estimate quantitatively the contribution of the charge-transfer complex (CTC) and the free monomers in the copolymerization process. The propagation reactivity ratios of CTC and free monomers were calculated by a new method. (C) 1997 John Wiley & Sons, Inc.

引用

页码：1535 / 1542

页数：8

共 14 条

[1] The mechanism of copolymerilzatlon
Alfrey, T
Goldfinger, G
[J]. JOURNAL OF CHEMICAL PHYSICS, 1944, 12 (06) : 205 - 209
[2] FREE-RADICAL COPOLYMERIZATIONS OF N-PHENYL MALEIMIDE
BARRALESRIENDA, JM
GONZALEZDELACAMPA, JI
RAMOS, JG
[J]. JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1977, A 11 (02): : 267 - 286
[3] NITROGEN-CONTAINING MONOMERS .1. COPOLYMERIZATION REACTIONS OF N-ALKYL MALEAMIC ACIDS AND N-ALKYL MALEIMIDES
COLEMAN, LE
CONRADY, JA
[J]. JOURNAL OF POLYMER SCIENCE, 1959, 38 (133): : 241 - 245
[4] POLYMERIZATION THERMODYNAMICS OF N-PHENYLMALEIMIDE AND ITS COPOLYMERIZATIONS WITH STYRENE AND PHENYL VINYL SULFIDE
IWATSUKI, S
KUBO, M
WAKITA, M
MATSUI, Y
KANOH, H
[J]. MACROMOLECULES, 1991, 24 (18) : 5009 - 5014
[5] ALTERNATING COPOLYMERIZATION OF STYRENE AND N-(4-BROMOPHENYL)MALEIMIDE
JANOVIC, Z
MATUSINOVIC, TT
RANOGAJEC, F
[J]. JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 1992, 29 (09): : 801 - 811
[6] MODEL COPOLYMERIZATION REACTIONS - EVIDENCE AGAINST PARTICIPATION OF A DONOR-ACCEPTOR COMPLEX IN REACTIONS OF THE L-BUTYL RADICAL WITH N-PHENYLMALEIMIDE AND STYRENE
JONES, SA
TIRRELL, DA
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1987, 25 (11) : 3177 - 3180
[7] RADICAL POLYMERIZATION OF N-(ALKYL-SUBSTITUTED PHENYL)MALEIMIDES - SYNTHESIS OF THERMALLY STABLE POLYMERS SOLUBLE IN NONPOLAR-SOLVENTS
MATSUMOTO, A
KUBOTA, T
OTSU, T
[J]. MACROMOLECULES, 1990, 23 (21) : 4508 - 4513
[8] COPOLYMERIZATION OF STYRENE WITH N-ARYLMALEIMIDES
MOHAMED, AA
JEBRAEL, FH
ELSABEE, MZ
[J]. MACROMOLECULES, 1986, 19 (01) : 32 - 37
[9] POLYMERIZATION AND COPOLYMERIZATION OF N-(4-CARBOXYPHENYL)MALEIMIDE
OISHI, T
IWAHARA, M
FUJIMOTO, M
[J]. POLYMER JOURNAL, 1991, 23 (12) : 1409 - 1417
[10] MODEL COPOLYMERIZATION REACTIONS - EVIDENCE AGAINST CONCERTED COMPLEX ADDITION IN REACTIONS OF SIMPLE ALKYL RADICALS WITH N-PHENYLMALEIMIDE AND DONOR OLEFINS
PREMENTINE, GS
JONES, SA
TIRRELL, DA
[J]. MACROMOLECULES, 1989, 22 (02) : 770 - 775

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