Metal-organic frameworks: Structures and functional applications

被引:943
作者
Jiao, Long [1 ]
Seow, Joanne Yen Ru [2 ]
Skinner, William Scott [2 ]
Wang, Zhiyong U. [2 ]
Jiang, Hai-Long [1 ]
机构
[1] Univ Sci & Technol China, Collaborat Innovat Ctr Suzhou Nano Sci & Technol, Hefei Natl Lab Phys Sci Microscale, Dept Chem, Hefei 230026, Anhui, Peoples R China
[2] Troy Univ, Dept Chem & Phys, Troy, AL 36082 USA
关键词
POROUS COORDINATION POLYMER; CARBON-DIOXIDE CAPTURE; EFFICIENT OXYGEN REDUCTION; HIGHLY EFFICIENT; METHANE STORAGE; WATER OXIDATION; MOISTURE-RESISTANT; HYDROGEN STORAGE; GAS-STORAGE; CATALYTIC-HYDROGENATION;
D O I
10.1016/j.mattod.2018.10.038
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Metal-organic frameworks (MOFs), constructed by organic linkers and metal nodes, are a new class of crystalline porous materials with significant application potentials. Featured with extremely high surface area, large porosity, tunable pore size, and flexible functionality, MOFs have gained extensive explorations as a highly versatile platform for functional applications in many research fields. This review presents an up-to-date summary ranging from the structural and physical properties of MOFs to their recent application advances including gas storage and separation, heterogeneous catalysis, chemical sensors, proton conductivity, biomedicine, and others. The structure-property relationships are particularly emphasized. Finally, the newly emerging research trends of MOFs and the unresolved challenges for functional applications are discussed in detail.
引用
收藏
页码:43 / 68
页数:26
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