Growth, thermal and optical properties of a new nonlinear optical crystal: ZnBi2B2O7

被引：14
|
作者：
Li, Nan [1 ,2 ]
Fu, Peizhen [1 ]
Wu, Yicheng [1 ]
Zhang, Jianxiu [1 ]
机构：
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Beijing Ctr Crystal Res & Dev, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
来源：
JOURNAL OF CRYSTAL GROWTH | 2009年 / 311卷 / 13期
基金：
中国国家自然科学基金;
关键词：
X-ray diffraction; Growth from melt; Bismuth and zincum borate; Nonlinear optical materials;
D O I：
10.1016/j.jcrysgro.2009.04.016
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Single crystals of ZnBi2B2O7 (ZBBO) have been successfully grown by the top-seeded growth method from a high-temperature melt. The crystal was colorless and transparent with size of 15 x 10 x 5 mm(3). The orientation of ZBBO crystal has been discussed. The melting point, molar enthalpy of fusion, and molar entropy of fusion of the crystal were determined to be 964.02K, 110680.36 J mol(-1), and 113.92 J K-1 mol(-1), respectively. The transparency range of the crystal extends from 370 to 2100 nm. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：3476 / 3478
页数：3
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