Electronic and molecular structures of polyanionic C60 fullerene and high-spin C60n- clusters studied by ESR/2D-electron spin transient nutation spectroscopy

被引：0

作者：

Shohoji, MCBL ^{[1
]}

Franco, MLTMB ^{[1
]}

Lazana, MCRLR ^{[1
]}

Nakazawa, S ^{[1
]}

Sato, K ^{[1
]}

Shiomi, D ^{[1
]}

Takui, T ^{[1
]}

机构：

[1] Univ Tecn Lisboa, Inst Super Tecn, Dept Chem, P-1096 Lisbon, Portugal

来源：

TWO-DIMENSIONAL CORRELATION SPECTROSCOPY | 2000年 / 503卷

关键词：

D O I：

暂无

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

A quartet state of trianionic C-60 fullerene was for the first time detected by ESR spectroscopy. The assignment of the spin-state quartet was confirmed unequivocally by pulsed ESR-based 2-dimensional electron spin transient nutation (2D-ESTN) spectroscopy. Spin Hamiltonian parameters of the quartet-state trianionic C-60 fullerene were determined by means of fine-structure spectral simulation: g=2.0025, \D\=0.0014cm(-1), E=0cm(-1). A quintet state of polyanionic C-60 clusters was also detected by 2D-ESTN spectroscopy.

引用

页码：333 / 336

页数：4

共 34 条

[31] Unraveling the Electron Spin Resonance Pattern of Nonsymmetric Radicals with 30 Fluorine Atoms: Electron Spin Resonance and Vis-Near-Infrared Spectroelectrochemistry of the Anion Radicals and Dianions of C60(CF3)2n (2n=2-10) Derivatives and Density Functional Theory-Assisted Assignment
Popov, Alexey A.
Kareev, Ivan E.
Shustova, Natalia B.
Strauss, Steven H.
Boltalina, Olga V.
Dunsch, Lothar
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (33) : 11709 - 11721
[32] MICROWAVE SPECTROSCOPY OF FULLERENE-BASED MOLECULAR SUPERCONDUCTORS IN LOW MAGNETIC-FIELD - MXC60 (M=K, RB, I2, GA, IN), MXCN (N=70, 76, 78, 84, 90) AND MX(C60)1-Y(C70)Y (M=K, RB)
ZAKHIDOV, AA
YAKUSHI, K
IMAEDA, K
INOKUCHI, H
KIKUCHI, K
SUZUKI, S
IKEMOTO, I
ACHIBA, Y
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1992, 216-18 : 299 - 306
[33] High-energy spectroscopic studies of the electronic structures of organic systems formed from carbon and fluorine by UPS, vacuum-UV optical spectroscopy, and NEXAFS:: Poly(hexafluoro-1,3-butadiene) [C(CF3) = C(CF3)]n, fluorinated graphites (CF, C2F, and C6F), perfluoroalkanes n-CnF2n+2, poly(tetrafluoroethylene) (CF2)n, and fluorinated fullerenes (C60Fx and C70Fx)
Seki, K
Mitsumoto, R
Ito, E
Araki, T
Sakurai, Y
Yoshimura, D
Ishii, H
Ouchi, Y
Miyamae, T
Narita, T
Nishimura, S
Takata, Y
Yokoyama, T
Ohta, T
Suganuma, S
Okino, F
Touhara, H
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2001, 355 : 247 - 274
[34] Electron spin resonance (ESR) spectroscopy of the transition-metal complexes and clusters -: I.: Systematic investigations of real- and complex-orbital methods for calculating the d-orbital energies of a low-spin (S = 1/2) nd5(t25, 2T2) (n = 3, 4, 5) system (I).: Calculation of the d-orbital energies in real- and complex-orbital representations for a low-spin nd5(t25, 2T2) (n = 3, 4, 5) system from a model of electronic-intersupplemental states
Zhao, K
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 1999, 18 (01) : 69 - 78

← 1 2 3 4 →