Electronic and molecular structures of polyanionic C60 fullerene and high-spin C60n- clusters studied by ESR/2D-electron spin transient nutation spectroscopy

被引：0

作者：

Shohoji, MCBL ^{[1
]}

Franco, MLTMB ^{[1
]}

Lazana, MCRLR ^{[1
]}

Nakazawa, S ^{[1
]}

Sato, K ^{[1
]}

Shiomi, D ^{[1
]}

Takui, T ^{[1
]}

机构：

[1] Univ Tecn Lisboa, Inst Super Tecn, Dept Chem, P-1096 Lisbon, Portugal

来源：

TWO-DIMENSIONAL CORRELATION SPECTROSCOPY | 2000年 / 503卷

关键词：

D O I：

暂无

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

A quartet state of trianionic C-60 fullerene was for the first time detected by ESR spectroscopy. The assignment of the spin-state quartet was confirmed unequivocally by pulsed ESR-based 2-dimensional electron spin transient nutation (2D-ESTN) spectroscopy. Spin Hamiltonian parameters of the quartet-state trianionic C-60 fullerene were determined by means of fine-structure spectral simulation: g=2.0025, \D\=0.0014cm(-1), E=0cm(-1). A quintet state of polyanionic C-60 clusters was also detected by 2D-ESTN spectroscopy.

引用

页码：333 / 336

页数：4

共 34 条

[1] Electronic quartet and triplet states of polyanionic C60 fullerene and their anomalous spin relaxation as studied by cw-ESR/2D-Electron spin transient nutation spectroscopy
Shohoji, MCBL
Franco, MLTMB
Lazana, MCRLR
Nakazawa, S
Sato, K
Shiomi, D
Takui, T
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (12) : 2962 - 2963
[2] Electronic quartet and triplet states of polyanionic C60 fullerene and their anomalous spin relaxation as studied by cw-ESR/2D-electron spin transient nutation spectroscopy
1600, (ACS, Washington, DC, USA):
[3] Electronic and molecular structures of C60-based polyanionic high-spin molecular clusters:: Direct spin identification and electron spin transient nutation spectroscopy for high-spin chemistry
Nakazawa, Shigeaki
Sato, Kazunobu
Shiomi, Daisuke
Franco, M. Luisa T. M. B.
Lazana, M. Celina R. L. R.
Shohoji, M. Candida B. L.
Itoh, Koichi
Takui, Takeji
INORGANICA CHIMICA ACTA, 2008, 361 (14-15) : 4031 - 4037
[4] Electronic states of polyanionic high-spin C60 fullerene and their clusters:: anomalous spin relaxation and Jahn-Teller effects
Nakazawa, S
Sato, K
Shiomi, D
Franco, MLTMB
Lazana, MCRLR
Shohoji, MCBL
Takui, T
SYNTHETIC METALS, 2001, 121 (1-3) : 1169 - 1170
[5] Pulsed ESR/2D-electron spin transient nutation study of stable high-spin polycarbenes
Sato, K
Shiomi, D
Takui, T
Hattori, M
Hirai, K
Tomioka, H
SYNTHETIC METALS, 2001, 121 (1-3) : 1816 - 1817
[6] Electronic and molecular structures of dendrimeric high-spin polycarbenes as studied by CW and pulsed ESR-based electron spin transient nutation spectroscopy
Sato, K
Shiomi, D
Takui, T
Hattori, M
Hirai, K
Tomioka, H
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2002, 376 : 549 - 554
[7] Electronic states and spin characterization of polyanionic high-spin molecules and clusters derived from 1,3-dibenzoylbenzene derivatives as studied by ESR/electron spin transient nutation spectroscopy
Nakazawa, S
Sato, K
Shiomi, D
Yano, M
Kinoshita, T
Abe, K
Takui, T
Itoh, K
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1999, 334 : 11 - 21
[8] Electronic States and Spin Characterization of Polyanionic High-Spin Molecules and Clusters Derived from 1,3-Dibenzoylbenzene Derivatives as Studied by ESR/Electron Spin Transient Nutation Spectroscopy
Nakazawa, Shigeaki
Sato, Kazunobu
Shiomi, Daisuke
Yano, Masafumi
Kinoshita, Takamasa
Abe, Kyo
Takui, Takeji
Itoh, Koichi
Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 334 : 11 - 21
[9] 2D-electron spin transient nutation (2D-ESTN) study of a stable high-spin carbene (S=3)
Sato, K
Shiomi, D
Takui, T
Itoh, K
Hattori, M
Hirai, K
Tomioka, H
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1999, 334 : 81 - 88
[10] Electronic structures of HonC60 clusters (n=1-5):: High electron acceptability of C60
Nagao, S
Negishi, Y
Kato, A
Nakamura, Y
Nakajima, A
Kaya, K
JOURNAL OF CHEMICAL PHYSICS, 2002, 117 (07): : 3169 - 3172

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