Synthesis and electrochemistry of meso-substitutes dipyrromethene nickel (II) complexes

被引：11
|
作者：
Wang, Yemei [1 ]
Xue, Zhaoli [1 ]
Dong, Yuan [1 ]
Zhu, Weihua [1 ]
机构：
[1] Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Peoples R China
来源：
POLYHEDRON | 2015年 / 102卷
基金：
中国博士后科学基金;
关键词：
Electrochemistry; Dipyrromethene; Metalation; Spectroelectrochemistry; Synthesis; TRANSITION-METAL-COMPLEXES; STRUCTURAL-CHARACTERIZATION; BODIPY DYES; ALPHA; ALPHA-DIPYRROLYLMETHENE; TETRAPHENYLPORPHYRIN; HYDROBROMIDES; DERIVATIVES; CHEMISTRY; DIPYRRINS; ZN(II);
D O I：
10.1016/j.poly.2015.10.020
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Metalation of dipyrromethene (dipyrrin) (la-c) with Ni(OAc)(2) provides Ni-dipyrrole complexes (NiL2) (2a-c) in 37-47% yields. The complexes were characterized by mass spectrometry and UV-Vis absorption, H-1 NMR spectroscopy and single crystal X-ray. In CH2Cl2, each compound undergoes two reversible one-electron reductions and one irreversible oxidation wave. In DMF, complexes 2a-c also undergoes two reversible one-electron reductions but with three irreversible oxidation waves were observed. The effect of substituents and solvent on redox potentials is discussed. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：578 / 582
页数：5
相关论文
共 50 条
  • [21] Synthesis, Characterization, and Electrochemistry of the Manganese(I) Complexes of meso-Substituted [14]Tribenzotriphyrins(2.1.1)
    Xue, Zhaoli
    Wang, Yemei
    Mack, John
    Zhu, Weihua
    Ou, Zhongping
    CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (05) : 2045 - 2051
  • [22] Synthesis, characterization and biological evaluation of cobalt(II), nickel(II) and copper(II) complexes of Schiff base
    Kurtoglu, Mukerrem
    Ispir, Esin
    ASIAN JOURNAL OF CHEMISTRY, 2007, 19 (02) : 1239 - 1245
  • [23] Synthesis, structure, and properties of palladium(ii) complex of α-formyl pyrrolyl dipyrromethene
    Panchavarnam, Sabari
    Sengupta, Rima
    Ravikanth, Mangalampalli
    DALTON TRANSACTIONS, 2022, 51 (14) : 5587 - 5595
  • [24] Synthesis, characterization and electrochemistry of phenyl-functionalized diiron propanedithiolate complexes
    Li, Chang-Gong
    Zhu, Yong
    Jiao, Xing-Xing
    Fu, Xiao-Qin
    POLYHEDRON, 2014, 67 : 416 - 421
  • [25] Synthesis, structure and electrochemistry of ruthenium(II) and (III) mono-and bis-oxalato complexes
    Elnajjar, Fawzia O.
    Wang, Ruiyao
    Aquino, Manuel A. S.
    INORGANICA CHIMICA ACTA, 2020, 502
  • [26] Platinum(II) and platinum(IV) porphyrin complexes: Synthesis, characterization, and electrochemistry
    Mink, LM
    Neitzel, ML
    Bellomy, LM
    Falvo, RE
    Boggess, RK
    Trainum, BT
    Yeaman, P
    POLYHEDRON, 1997, 16 (16) : 2809 - 2817
  • [27] Synthesis and characterization of some heteroleptic copper(II) complexes based on meso-substituted dipyrrins
    Gupta, Rakesh Kumar
    Yadav, Mahendra
    Pandey, Rampal
    Pandey, Daya Shankar
    JOURNAL OF CHEMICAL SCIENCES, 2011, 123 (06) : 819 - 826
  • [28] Electrochemistry and Spectroscopy of Organometallic Terpyridine Nickel Complexes
    Hamacher, Claudia
    Hurkes, Natascha
    Kaiser, Andre
    Klein, Axel
    Schueren, Andreas
    INORGANIC CHEMISTRY, 2009, 48 (20) : 9947 - 9951
  • [29] Dimetallic thiolate-bridged complexes: synthesis and rich electrochemistry of dinickel(II) and dizinc(II) monothiolate complexes
    Brooker, S
    Croucher, PD
    Davidson, TC
    Smith, PD
    POLYHEDRON, 2000, 19 (16-17) : 1887 - 1894
  • [30] Oxovanadium(IV) and Nickel(II) complexes obtained from 2,2′-dihydroxybenzophenone-S-methyl-thiosemicarbazone: Synthesis, characterization, electrochemistry, and antioxidant capability
    Ilhan-Ceylan, Berat
    INORGANICA CHIMICA ACTA, 2021, 517
12345