Preparation and Characterization of Fe-Tetranitro Phthalocyanine/Polyurethane Blends

In this article, Fe-Tetranitro phthalocyanine (Fe-TNPc)/polyurethane (PU) blends were prepared by solution blending. The mechanical properties of the samples were studied by tensile tests. The results showed that the tensile strength and the elongation at break of the samples increased with increasing Fe-TNPc content. The improved mechanical properties for the samples containing Fe-TNPc was attributed to the increased microphase separation degree of PU, which was further investigated by dynamic mechanical analysis (DMA) and Fourier transform infrared analysis. The lower T-g of the soft segments and the higher T-g of the hard segments for the samples containing Fe-TNPc indicated an increase of microphase separation degree of PU. The increased hydrogen bonded carbonyl groups in the samples with increasing Fe-TNPc content also proved the conclusion. Quantitative evaluation of the interaction between Fe-TNPc and PU was also investigated by analyzing the physical crosslinking density of the samples. The results indicated that the physical crosslinking density of the samples increased with increasing Fe-TNPc content. The antibacterial properties of the samples were investigated. The results showed that the percentage bacterial inactivation toward S. aureus and E. coli of the samples were 98.9% and 90.9%, respectively, when Fe-TNPc was added to 1%. (c) 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41284.