Interaction of thin wetting films of lecithin with some divalent cations

被引:6
作者
Karabaliev, M
Kochev, V
机构
[1] Trakia Univ, Fac Med, Dept Phys & Biophys, Stara Zagora 6003, Bulgaria
[2] Sofia Univ Kl Ohridsky, Dept Atom Phys, Sofia 1164, Bulgaria
关键词
solid supported lipid films; model membrane; divalent cations; glassy carbon; impedimetry; cyclic voltammetry;
D O I
10.1016/j.bioelechem.2003.10.018
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The impact of some divalent cations on the structure of a model membrane system, comprising wetting lipid films, is assayed in this work. The results from impedimetry suggest prominent structural changes upon the addition of the discussed ions to the electrolyte solution contacting the film. These changes are manifested by the increase of resistivity of the films as well as by the decrease of capacitance dispersion. In accordance with other data in the literature, manganese (Mn2+) turned out to have an effect greater than those of Mg2+ and Ca2+. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:177 / 181
页数:5
相关论文
共 31 条
  • [1] Alberts B., 1983, MOL BIOL CELL
  • [2] CA-2+ BINDING TO PHOSPHATIDYLCHOLINE BILAYERS AS STUDIED BY DEUTERIUM MAGNETIC-RESONANCE - EVIDENCE FOR THE FORMATION OF A CA-2+ COMPLEX WITH 2 PHOSPHOLIPIDMOLECULES
    ALTENBACH, C
    SEELIG, J
    [J]. BIOCHEMISTRY, 1984, 23 (17) : 3913 - 3920
  • [3] Impedance measurements of self-assembled lipid bilayer membranes on the tip of an electrode
    Bordi, F
    Cametti, C
    Gliozzi, A
    [J]. BIOELECTROCHEMISTRY, 2002, 57 (01) : 39 - 46
  • [4] Studies of structural disorder of self-assembled thiol monolayers on gold by cyclic voltammetry and ac impedance
    Diao, P
    Jiang, DL
    Cui, XL
    Gu, DP
    Tong, RT
    Zhong, B
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1999, 464 (01) : 61 - 67
  • [5] GENNIS RB, 1989, BIOMEMBRANIES MOL ST
  • [6] Improvement of the quality of self assembled bilayer lipid membranes by using a negative potential
    Haas, H
    Lamura, G
    Gliozzi, A
    [J]. BIOELECTROCHEMISTRY, 2001, 54 (01): : 1 - 10
  • [7] Emerging techniques for investigating molecular interactions at lipid membranes
    Heyse, S
    Stora, T
    Schmid, E
    Lakey, JH
    Vogel, H
    [J]. BIOCHIMICA ET BIOPHYSICA ACTA-REVIEWS ON BIOMEMBRANES, 1998, 1376 (03): : 319 - 338
  • [8] Hianik T, 2000, J Biotechnol, V74, P189, DOI 10.1016/S1389-0352(00)00015-5
  • [9] High electric resistance polymer/lipid composite films on indium-tin-oxide electrodes
    Hillebrandt, H
    Wiegand, G
    Tanaka, M
    Sackmann, E
    [J]. LANGMUIR, 1999, 15 (24) : 8451 - 8459
  • [10] Ca2+ induced Fe(CN)63-/4- electron transfer at Pt supported BLM electrode
    Jiang, DL
    Diao, P
    Tong, RT
    Gu, DP
    Zhong, B
    [J]. BIOELECTROCHEMISTRY AND BIOENERGETICS, 1998, 44 (02): : 285 - 288