Catalytic upgrading of soybean oil methyl esters by partial hydrogenation using Pd catalysts

被引:38
作者
Thunyaratchatanon, Chachchaya [1 ]
Luengnaruemitchai, Apanee [1 ]
Chollacoop, Nuwong [2 ]
Yoshimura, Yuji [3 ]
机构
[1] Chulalongkorn Univ, Petr & Petrochem Coll, Soi Chula 12,Phayathai Rd, Bangkok 10330, Thailand
[2] Natl Met & Mat Technol Ctr, Klongluang 12120, Pathumthani, Thailand
[3] Natl Inst Adv Ind Sci & Technol, Tsukuba Cent 5, Tsukuba, Ibaraki 3058565, Japan
关键词
Soybean oil; Biodiesel; Partial hydrogenation; Oxidative stability; Cold flow properties; NOBLE-METAL CATALYSTS; BIODIESEL PRODUCTION; SELECTIVE HYDROGENATION; SULFUR TOLERANCE; LOW-TEMPERATURE; VEGETABLE-OILS; SILICA; PLATINUM; ACID; SUPPORT;
D O I
10.1016/j.fuel.2015.09.026
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Fatty acid methyl esters derived from soybean oil were partially hydrogenated over three types of catalysts-Pd, Pt, and Ni-supported on SiO2. The effect of the sulfur compounds on catalytic activity of the three noble metals was investigated. In both hydrogenated biodiesel with and without additional sulfur compounds, the turnover frequency (TOF) for partial hydrogenation over Pd/SiO2 was greater than that over the Pt/SiO2 and Ni/SiO2 catalysts. On the other hand, Pt/SiO2 exhibited the most sulfur tolerance. Partially hydrogenated biodiesel were found to have better oxidative stability compared to non-hydrogenated biodiesel. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:8 / 16
页数:9
相关论文
共 50 条
[31]   Studies in catalytic transfer hydrogenation of soybean oil using ammonium formate as donor over 5% Pd/C catalyst [J].
Tike, Manoj A. ;
Mahajani, Vijaykumar V. .
CHEMICAL ENGINEERING JOURNAL, 2006, 123 (1-2) :31-41
[32]   Effect of silver modification on structure and catalytic performance of Ni-Mg/diatomite catalysts for edible oil hydrogenation [J].
Stankovic, Miroslav ;
Gabrovska, Margarita ;
Krstic, Jugoslav ;
Tzvetkov, Peter ;
Shopska, Maya ;
Tsacheva, Tsenka ;
Bankovic, Predrag ;
Edreva-Kardjieva, Rumeana ;
Jovanovic, Dusan .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 297 (01) :54-62
[33]   Selective catalytic transfer hydrogenation of polyunsaturated fatty acid methyl esters using Pd/organobentonite as catalyst under microwave heating [J].
Lu, Chong ;
Gao, Lei ;
Zhang, Linye ;
Liu, Kun ;
Hou, Yingchun ;
He, Tianqiu ;
Zhou, Yanling ;
Wei, Guangtao .
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2022, 182
[34]   Preparation and fuel properties of mixtures of soybean oil methyl and ethyl esters [J].
Joshi, Hem ;
Moser, Bryan R. ;
Toler, Joe ;
Walker, Terry .
BIOMASS & BIOENERGY, 2010, 34 (01) :14-20
[35]   Biomass Nanoporous Carbon-Supported Pd Catalysts for Partial Hydrogenation of Biodiesel: Effects of Surface Chemistry on Pd Particle Size and Catalytic Performance [J].
Udomsap, Parncheewa ;
Meesiri, Sirasit ;
Chollacoop, Nuwong ;
Eiad-Ua, Apiluck .
NANOMATERIALS, 2021, 11 (06)
[36]   Catalytic selective hydrogenation of soybean oil for industrial intermediates [J].
Lee, Kyu-Wan ;
Mei, Bai Xue ;
Bo, Quan ;
Kim, Young-Wun ;
Chung, Keun-Woo ;
Han, Yohan .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2007, 13 (04) :530-536
[37]   Efficacy of myricetin as an antioxidant in methyl esters of soybean oil [J].
Moser, Bryan R. .
EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY, 2008, 110 (12) :1167-1174
[38]   Continuous production of fatty acid methyl esters from soybean oil deodorized distillate and methyl acetate at supercritical conditions [J].
Vernier, Liara Jalime ;
Nunes, Ana Luiza Barrachini ;
Albarello, Mariana ;
de Castilhos, Fernanda .
JOURNAL OF SUPERCRITICAL FLUIDS, 2022, 186
[39]   Partial hydrogenation of methyl esters of sunflower oil catalyzed by highly active rhodium sulfonated triphenylphosphite complexes [J].
Nikolaou, Nikolaos ;
Papadopoulos, Christos E. ;
Lazaridou, Anastasia ;
Koutsoumba, Asimina ;
Bouriazos, Achilleas ;
Papadogianakis, Georgios .
CATALYSIS COMMUNICATIONS, 2009, 10 (05) :451-455
[40]   Selective Hydrogenation of Soybean Oil on Copper Catalysts as a Tool Towards Improved Bioproducts [J].
Trasarti, A. F. ;
Segobia, D. J. ;
Apesteguia, C. R. ;
Santoro, F. ;
Zaccheria, F. ;
Ravasio, N. .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2012, 89 (12) :2245-2252