Prediction and correlation of viscosity of binary mixtures of ionic liquids with organic solvents

被引:28
作者
Bajic, Divna M. [1 ]
Serbanovic, Slobodan P. [1 ]
Zivkovic, Emila M. [1 ]
Jovanovic, Jovan [1 ]
Kijevcanin, Mirjana Lj [1 ]
机构
[1] Univ Belgrade, Fac Technol & Met, Belgrade 11120, Serbia
关键词
Viscosity; Ionic liquid; Prediction; Correlation; UNIFAC-VISCO; KINEMATIC VISCOSITY; PHYSICAL-PROPERTIES; REFRACTIVE-INDEXES; DENSITIES; TETRAFLUOROBORATE; MODEL; NRTL;
D O I
10.1016/j.molliq.2014.04.005
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Viscosities of ten binary liquid mixtures consisting of ionic liquids and organic compounds, determined at atmospheric pressure and in a wide temperature range, were calculated using two different approaches, predictive by group contribution models (UNIFAC-VISCO and ASOG-VISCO) and correlative (Seddon, Grunberg-Nissan, McAlister, Eyring-UNIQUAC and Eyring-NRTL models), and compared using literature data. The obtained results were analysed in terms of the applied approach and model. For UNIFAC-VISCO and ASOG-VISCO predictive models, the literature viscosity data were used to determine new interaction parameters. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 6
页数:6
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