Novel chromogenic macrocyclic molecular probes with logic gate function using anion/cation inputs

被引：9

作者：

Garcia, Veronica ^{[1
]}

Fernandez-Lodeiro, Adrian ^{[2
,3
]}

Lamelas, Rodrigo ^{[1
]}

Macias, Alejandro ^{[1
]}

Bastida, Rufina ^{[1
]}

Bertolo, Emilia

Nunez, Cristina ^{[1
,2
,4
]}

机构：

[1] Univ Santiago de Compostela, Fac Chem, Dept Inorgan Chem, Santiago De Compostela 15782, Spain

[2] Univ Nova Lisboa, Fac Sci & Technol, Dept Chem, REQUIMTE, P-2829516 Monte De Caparica, Portugal

[3] ProteoMass Sci Soc, P-2825182 Caparica, Portugal

[4] Canterbury Christ Church Univ, Dept Geog & Life Sci, Ecol Res Grp, Canterbury CT1 1QU, Kent, England

来源：

DYES AND PIGMENTS | 2014年 / 110卷

关键词：

Logic gate; Sensors; Colorimetric; Anions; Cu2+; Hg2+; RECEPTOR CHEMISTRY HIGHLIGHTS; SIDE-ARMS; ANION; RECOGNITION; POLYAMINES; LIGANDS; SYSTEMS; UREA;

D O I：

10.1016/j.dyepig.2014.04.023

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Two novel macrocyclic molecular probes linked to two nitrophenylurea and two nitrophenylthiourea groups, respectively, are reported. It was found that these systems can recognize different anions (OH-, F-, CN- with the nitrophenylurea probe, and OH-, F-, CN-, CH3COO- and H2PO4- with the nitrophenylthiourea probe) resulting in a red shift of electronic transition and correspondingly color-switching the probes. In addition, based on above sensing mechanism with the probes, IFNOT logic operations can be achieved using OH- and Cu2+ ion as inputs, and/or F- and Hg2+, respectively, making the probes, promising candidate for further applications in molecular logic devices. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：143 / 151

页数：9

共 28 条

[1] Colorimetric macrocyclic anion probes bearing nitrophenylurea and nitrophenylthiourea binding groups [J].

Aldrey, Anxela ;

Garcia, Veronica ;

Lodeiro, Carlos ;

Macias, Alejandro ;

Perez-Lourido, Paulo ;

Valencia, Laura ;

Bastida, Rufina ;

Nunez, Cristina .

TETRAHEDRON, 2013, 69 (23) :4578-4585

[2] A chemosensor for dihydrogenphosphate based on an oxoazamacrocycle possessing three thiourea arms [J].

Aldrey, Anxela ;

Macias, Alejandro ;

Bastida, Rufina ;

Zaragoza, Guillermo ;

Rama, Gustavo ;

Vazquez Lopez, Miguel .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2012, 10 (28) :5379-5384

[3] Anion sensing properties of new colorimetric chemosensors based on macrocyclic ligands bearing three nitrophenylurea groups [J].

Aldrey, Anxela ;

Nunez, Cristina ;

Garcia, Veronica ;

Bastida, Rufina ;

Lodeiro, Carlos ;

Macias, Alejandro .

TETRAHEDRON, 2010, 66 (47) :9223-9230

[4] Macrocyclic ligands bearing two 3-(Hydroxy)-2-pyridinone moieties as side-arms. Conformational studies, synthesis, crystal structure, and alkali and alkaline earth complex formation [J].

Ambrosi, G ;

Dapporto, P ;

Formica, M ;

Fusi, V ;

Giorgi, L ;

Guerri, A ;

Lucarini, S ;

Micheloni, M ;

Paoli, P ;

Pontellini, R ;

Rossi, P ;

Zappia, G .

NEW JOURNAL OF CHEMISTRY, 2004, 28 (11) :1359-1367

[5] Some guidelines for the design of anion receptors [J].

Amendola, Valeria ;

Bonizzoni, Marco ;

Esteban-Gomez, David ;

Fabbrizzi, Luigi ;

Licchelli, Maurizio ;

Sancenon, Felix ;

Taglietti, Angelo .

COORDINATION CHEMISTRY REVIEWS, 2006, 250 (11-12) :1451-1470

[6]

[Anonymous], ORG BIOMOL CHEM

[7]

[Anonymous], SHELX97 INTEGRATED S

[8]

[Anonymous], SHELXTL VERS INT SYS

[9] ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI) [J].

Barnes, CL .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1997, 30 (01) :568-568

[10] Colorimetric Logic Gates Based on Supramolecular DNAzyme Structures [J].

Bi, Sai ;

Yan, Yameng ;

Hao, Shuangyuan ;

Zhang, Shusheng .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (26) :4438-4442

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