Pd(0)-guanidine@MCM-41 as efficient and reusable heterogeneous catalyst for C-C coupling reactions

被引：23

作者：

Filian, Hossein ^{[1
,2
]}

Ghorbani-Choghamarani, Arash ^{[3
]}

Tahanpesar, Elham ^{[2
]}

机构：

[1] Islamic Azad Univ, Khuzestan Sci & Res Branch, Dept Chem, Ahvaz, Iran

[2] Islamic Azad Univ, Ahvaz Branch, Dept Chem, Ahvaz, Iran

[3] Ilam Univ, Dept Chem, Fac Sci, POB 69315516, Ilam, Iran

来源：

JOURNAL OF POROUS MATERIALS | 2019年 / 26卷 / 04期

关键词：

Mesoporous MCM-41; Palladium; Stille reaction; Suzuki reaction; Guanidine; MAGNETIC NANOPARTICLES; PHOSPHINE-FREE; FUNCTIONALIZED MCM-41; HIGHLY EFFICIENT; PD NANOPARTICLES; HECK REACTIONS; SUZUKI; PALLADIUM; COMPLEX; NANOCATALYST;

D O I：

10.1007/s10934-018-0698-9

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A new catalyst of palladium containing guanidine as stabilizer ligand grafted on functionalized MCM-41 (Pd(0)-guanidine@MCM-41) was prepared during post-grafting procedure and characterized by SEM, EDS, WDX, BET, TEM, TGA, ICP and FT-IR techniques. Further this catalyst was used as efficient and recyclable nanocatalyst for the carbon-carbon cross-coupling reactions such as Suzuki and Stille reactions. Biphenyls were synthesized in short reaction times and high yields in the presence of this catalyst. This catalyst was reused up to 10 times in Suzuki reaction that shows high recyclability of this catalyst.

引用

页码：1091 / 1101

页数：11

共 42 条

[21] Cephalosporin release from functionalized MCM-41 supports interpreted by various models [J].

Maria, Gheorghe ;

Stoica, Anca-Lulia ;

Luta, Ionela ;

Stirbet, Daniela ;

Radu, Gabriel Lucian .

MICROPOROUS AND MESOPOROUS MATERIALS, 2012, 162 :80-90

[22] Palladium nanoparticles embedded on mesoporous TiO2 material (Pd@MTiO2) as an efficient heterogeneous catalyst for Suzuki-Coupling reactions in water medium [J].

Mondal, Paramita ;

Bhanja, Piyali ;

Khatunar, Resmin ;

Bhaumik, Asim ;

Das, Debasis ;

Islam, Sk. Manirul .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2017, 508 :378-386

[23] Efficient synthesis of 5-substituted tetrazoles catalysed by palladium-S-methylisothiourea complex supported on boehmite nanoparticles [J].

Moradi, Parisa ;

Ghorbani-Choghamarani, Arash .

APPLIED ORGANOMETALLIC CHEMISTRY, 2017, 31 (05)

[24] Efficient Heterogeneous Gold(I)-Catalyzed Direct C(sp2)-C(sp) Bond Functionalization of Arylalkynes through a Nitrogenation Process to Amides [J].

Nie, Quan ;

Yi, Feiyan ;

Huang, Bin ;

Cai, Mingzhong .

ADVANCED SYNTHESIS & CATALYSIS, 2017, 359 (22) :3968-3976

[25] Synthesis and characterization of Cu(II)-Adenine-MCM-41 as stable and efficient mesoporous catalyst for the synthesis of 5-substituted 1H-tetrazoles and 1H-indazolo [1,2-b]phthalazine-triones [J].

Nikoorazm, Mohsen ;

Ghorbani-Choghamaranai, Arash ;

Khanmoradi, Maryam ;

Moradi, Parisa .

JOURNAL OF POROUS MATERIALS, 2018, 25 (06) :1831-1842

[26] Pd(0)-Schiff-base@MCM-41 as high-efficient and reusable catalyst for C-C coupling reactions [J].

Nikoorazm, Mohsen ;

Ghorbani-Choghamarani, Arash ;

Panahi, Atefeh ;

Tahmasbi, Bahman ;

Noori, Nourolah .

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2018, 15 (01) :181-189

[27] A palladium complex immobilized onto mesoporous silica: a highly efficient and reusable catalytic system for carbon-carbon bond formation and anilines synthesis [J].

Nikoorazm, Mohsen ;

Noori, Nourolah ;

Tahmasbi, Bahman ;

Faryadi, Sara .

TRANSITION METAL CHEMISTRY, 2017, 42 (05) :469-481

[28] Palladium 2-mercapto-N-propylacetamide complex anchored onto MCM-41 as efficient and reusable nanocatalyst for Suzuki, Stille and Heck reactions and amination of aryl halides [J].

Nikoorazm, Mohsen ;

Ghorbani-Choghamarani, Arash ;

Noori, Nourolah ;

Tahmasbi, Bahman .

APPLIED ORGANOMETALLIC CHEMISTRY, 2016, 30 (10) :843-851

[29] Immobilization of palladium on functionalized nanoporous MCM-41 and its application in C-C bond-forming and synthesis of DHQs [J].

Nikoorazm, Mohsen ;

Ghorbani-Choghamarani, Arash ;

Khanmoradi, Maryam .

JOURNAL OF POROUS MATERIALS, 2016, 23 (03) :761-772

[30] Polyaniline-anchored palladium catalyst-mediated Mizoroki-Heck and Suzuki-Miyaura reactions and one-pot Wittig-Heck and Wittig-Suzuki reactions [J].

Patel, Heta A. ;

Patel, Arun L. ;

Bedekar, Ashutosh V. .

APPLIED ORGANOMETALLIC CHEMISTRY, 2015, 29 (01) :1-6

← 1 2 3 4 5 →