Preparation of 1,1'-Oxy-bis(3,3-bis(trifluoromethyl)-3(1H)-1,2-benziodoxole) and 2-(N-(p-Toluenesulfonyl)imino)iodobenzylmethyl Ether

被引：18

作者：

Blake, Alexander J. ^{[1
]}

Novak, Andrew ^{[1
]}

Davies, Madeline ^{[1
]}

Robinson, Richard I. ^{[1
]}

Woodward, Simon ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

SYNTHETIC COMMUNICATIONS | 2009年 / 39卷 / 06期

关键词：

Alkene functionalization; hypervalent iodine reagents; nitrene precursor; x-ray; CYCLIC SULFATES; REAGENTS; ALCOHOLS;

D O I：

10.1080/00397910802474990

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Conditions for improved preparation of the crystalline iodine(III) reagents [1,2-C6H4(C(CF3)2OI)]2O and 1,2-C6H4(CH2OMe)(I=NTs) are presented together with their x-ray structures. The former is prepared by hydrolysis of 1,2-C6H4(C(CF3)2OICl (x-ray) and allows the preparation of cyclic sulfates from alkenes; the latter fashions sulfamidate under related conditions.

引用

页码：1065 / 1075

页数：11

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